Question

Determine the ph of a 0.18 m h2co3 solution. carbonic acid is a diprotic acid whose ka1 = 4.3 × 10-7 and ka2 = 5.6 × 10-11. determine the ph of a 0.18 m h2co3 solution. carbonic acid is a diprotic acid whose ka1 = 4.3 × 10-7 and ka2 = 5.6 × 10-11. 4.31 5.50 11.00 10.44 3.56

Answer 1

Answer is: ph value is 3.56.
Chemical reaction 1: H₂CO₃(aq) ⇄ HCO₃⁻(aq) + H⁺(aq); Ka₁ = 4,3·10⁻⁷.
Chemical reaction 2: HCO₃⁻(aq) ⇄ CO₃²⁻(aq) + H⁺(aq); Ka₂ = 5,6·10⁻¹¹.
c(H₂CO₃) = 0,18 M.
[HCO₃⁻] = [H⁺] = x.
[H₂CO₃] = 0,18 M - x.
Ka₁ = [HCO₃⁻] · [H⁺] / [H₂CO₃].
4,3·10⁻⁷ = x² / (0,18 M -x).
Solve quadratic equation: x = [H⁺] =0,000293 M.
pH = -log[H⁺] = -log(0,000293 M).
pH = 3,56; second Ka do not contributes pH value a lot.