<u>Answer:</u> The volume of concentrated solution required is 9.95 mL
<u>Explanation:</u>
To calculate the pH of the solution, we use the equation:
![pH=-\log[H^+]](https://tex.z-dn.net/?f=pH%3D-%5Clog%5BH%5E%2B%5D)
We are given:
pH = 0.70
Putting values in above equation, we get:
![0.70=-\log[H^+]](https://tex.z-dn.net/?f=0.70%3D-%5Clog%5BH%5E%2B%5D)
![[H^+]=10^{-0.70}=0.199M](https://tex.z-dn.net/?f=%5BH%5E%2B%5D%3D10%5E%7B-0.70%7D%3D0.199M)
1 mole of nitric acid produces 1 mole of hydrogen ions and 1 mole of nitrate ions.
Molarity of nitric acid = 0.199 M
To calculate the volume of the concentrated solution, we use the equation:
where,
are the molarity and volume of the concentrated nitric acid solution
are the molarity and volume of diluted nitric acid solution
We are given:
Putting values in above equation, we get:
Hence, the volume of concentrated solution required is 9.95 mL
The new pH is 7.69.
According to Hendersen Hasselbach equation;
The Henderson Hasselbalch equation is an approximate equation that shows the relationship between the pH or pOH of a solution and the pKa or pKb and the ratio of the concentrations of the dissociated chemical species. To calculate the pH of the buffer solution made by mixing salt and weak acid/base. It is used to calculate the pKa value. Prepare buffer solution of needed pH.
pH = pKa + log10 ([A–]/[HA])
Here, 100 mL of 0.10 m TRIS buffer pH 8.3
pka = 8.3
0.005 mol of TRIS.
∴ ![8.3 = 8.3 + log \frac{[0.005]}{[0.005]}](https://tex.z-dn.net/?f=8.3%20%3D%208.3%20%2B%20log%20%5Cfrac%7B%5B0.005%5D%7D%7B%5B0.005%5D%7D)
<em> </em>inverse log 0 = ![\frac{[B]}{[A]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BB%5D%7D%7B%5BA%5D%7D)
![\frac{[B]}{[A]} = 1](https://tex.z-dn.net/?f=%5Cfrac%7B%5BB%5D%7D%7B%5BA%5D%7D%20%3D%201)
Given; 3.0 ml of 1.0 m hcl.
pka = 8.3
0.003 mol of HCL.
![pH = 8.3 + log \frac{[0.005-0.003]}{[0.005+0.003]}\\pH = 8.3 + log \frac{[0.002]}{[0.008]}\\\\pH = 8.3 + log {0.25}\\\\pH = 8.3 + (-0.62)\\pH = 7.69](https://tex.z-dn.net/?f=pH%20%3D%208.3%20%2B%20log%20%5Cfrac%7B%5B0.005-0.003%5D%7D%7B%5B0.005%2B0.003%5D%7D%5C%5CpH%20%3D%208.3%20%2B%20log%20%5Cfrac%7B%5B0.002%5D%7D%7B%5B0.008%5D%7D%5C%5C%5C%5CpH%20%3D%208.3%20%2B%20log%20%7B0.25%7D%5C%5C%5C%5CpH%20%3D%208.3%20%2B%20%28-0.62%29%5C%5CpH%20%3D%207.69)
Therefore, the new pH is 7.69.
Learn more about pH here:
brainly.com/question/24595796
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