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muminat
4 years ago
5

Given the following reactions

8g%29" id="TexFormula1" title="2S (s) + 3O_2 (g) \rightarrow 2SO_3 (g)" alt="2S (s) + 3O_2 (g) \rightarrow 2SO_3 (g)" align="absmiddle" class="latex-formula">, ΔH = -790 kJ S (s) + O_2 (g) \rightarrow SO_2 (g), ΔH = -297 kJ The enthalpy of the reaction in which sulfur dioxide is oxidized to sulfur trioxide 2SO_2 (g) + O_2 (g) \rightarrow 2SO_3 (g) is ________ kJ.
Chemistry
1 answer:
Viefleur [7K]4 years ago
4 0

Answer:

ΔH = -196 kJ

Explanation:

To do this, we need to apply the Hess's law, which states the following:

<em>"The heat of any reaction     ΔHf°  for a specific reaction is equal to the sum of the heats of reaction for any set of reactions which in sum are equivalent to the overall reaction."</em>

This means that if we have the reaction:

2SO2 + O2 ------> 2SO3

We need to write and rearrange the given reactions, in order, to give this final reaction.  

For the first reaction we have:

2S(s) + 3O2(g) -----> 2 SO3(g)  ΔH = -790 kJ

As we can see, we have the SO3 as product, (Like the overall reaction), so by logic, we should rearrange the second reaction:

S(s) + O2(g) -----> SO2(g)

To rearrange, we only reverse the reaction and then, double the coefficients. Doing this, we have the following:

2SO2(g) ----> 2 S(s)+ 2 O2(g)       2(ΔH = 297kJ)  

As the reaction is reversed, the sign of ΔH is reversed too.

Now, putting both reactions:

2S(s) + 3O2(g) -----> 2SO3(g)

2SO2(g) ----> 2S(s)+ 2O2(g)

Simplyfing we have the overall reaction (Sulfur cancels, and O2 is substrated, leaving one molecule of O2).

2SO2(g) + O2(g) --> 2SO3(g)

So all we have to do is sum the enthalpy of reaction of both equations, and the result would be the enthalpy of reaction of the sulfur trioxide:  

ΔHrxn = -790 kJ + 2(297 kJ) = -196 kJ

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