A decrease in the amount of gas in a container will mean a decrease in pressure.
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Answer:

Explanation:
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In this case, when we want to balance chemical reactions such as in this case, the idea is to equal to number of atoms of each element at each side of the equation according to the lay of conservation of mass, just as shown below:

Because we have four phosphorous and ten oxygen atoms at each side.
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Answer:
6.4 × 10^-10 M
Explanation:
The molar solubility of the ions in a compound can be calculated from the Ksp (solubility constant).
CaF2 will dissociate as follows:
CaF2 ⇌Ca2+ + 2F-
1 mole of Calcium ion (x)
2 moles of fluorine ion (2x)
NaF will also dissociate as follows:
NaF ⇌ Na+ + F-
Where Na+ = 0.25M
F- = 0.25M
The total concentration of fluoride ion in the solution is (2x + 0.25M), however, due to common ion effect i.e. 2x<0.25, 2x can be neglected. This means that concentration of fluoride ion will be 0.25M
Ksp = {Ca2+}{F-}^2
Ksp = {x}{0.25}^2
4.0 × 10^-11 = 0.25^2 × x
4.0 × 10^-11 = 0.0625x
x = 4.0 × 10^-11 ÷ 6.25 × 10^-2
x = 4/6.25 × 10^ (-11+2)
x = 0.64 × 10^-9
x = 6.4 × 10^-10
Therefore, the molar solubility of CaF2 in NaF solution is 6.4 × 10^-10M