Answer:
V₂ = 0.656 L
Explanation:
Given data:
Initial volume = 3.5 L
Initial pressure = 2.5 KPa
Final volume = ?
Final pressure = 100 mmHg (100/7.501=13.33 KPa)
Solution:
The given problem will be solved through the Boyle's law,
"The volume of given amount of gas is inversely proportional to its pressure by keeping the temperature and number of moles constant"
Mathematical expression:
P₁V₁ = P₂V₂
P₁ = Initial pressure
V₁ = initial volume
P₂ = final pressure
V₂ = final volume
Now we will put the values in formula,
P₁V₁ = P₂V₂
2.5 KPa × 3.5 L = 13.33 KPa × V₂
V₂ = 8.75 KPa. L/13.33 KPa
V₂ = 0.656 L
Explanation:
Equation of the reaction:
Br2(l) + Cl2(g) --> 2BrCl(g)
The enthalpy change for this reaction will be equal to twice the standard enthalpy change of formation for bromine monochloride, BrCl.
The standard enthalpy change of formation for a compound,
ΔH°f, is the change in enthalpy when one mole of that compound is formed from its constituent elements in their standard state at a pressure of 1 atm.
This means that the standard enthalpy change of formation will correspond to the change in enthalpy associated with this reaction
1/2Br2(g) + 1/2Cl2(g) → BrCl(g)
Here, ΔH°rxn = ΔH°f
This means that the enthalpy change for this reaction will be twice the value of ΔH°f = 2 moles BrCl
Using Hess' law,
ΔH°f = total energy of reactant - total energy of product
= (1/2 * (+112) + 1/2 * (+121)) - 14.7
= 101.8 kJ/mol
ΔH°rxn = 101.8 kJ/mol.
Answer:
ΔH = 
Explanation:
In a calorimeter, when there is a complete combustion within the calorimeter, the heat given off in the combustion is used to raise the thermal energy of the water and the calorimeter.
The heat transfer is represented by
=
where
= the internal heat gained by the whole calorimeter mass system, which is the water, as well as the calorimeter itself.
= the heat of combustion
Also, we know that the total heat change of the any system is
ΔH = ΔQ + ΔW
where
ΔH = the total heat absorbed by the system
ΔQ = the internal heat absorbed by the system which in this case is
ΔW = work done on the system due to a change in volume. Since the volume of the calorimeter system does not change, then ΔW = 0
substituting into the heat change equation
ΔH = + 0
==> ΔH =
