For your first question, that equation only works if your situation is occurring at a constant temperature. Your original question is such a situation - everything occurs at 298.15 K. Therefore, you can use this value in the equation to calculate work.
For your second question, Charles' Law describes how the volume of gas changes as you heat or cool it, PROVIDED PRESSURE AND MOLES OF GAS REMAIN CONSTANT THE WHOLE TIME. In your original question above, temperature stays constant while volume changes. However, what they don't tell you is that this necessarily requires a change in either pressure or moles of gas. Because the question works with the same sample the of gas the whole time (i.e. moles are constant), it is pressure that is changing (and this change will occur according to Boyle's Law, since temperature and moles are held constant).
Hope that clarifies things!
Answer: 1145.8 years
Explanation:
Half-life of carbon-14 = 5720 years
First we have to calculate the rate constant, we use the formula :


Now we have to calculate the age of the sample:
Expression for rate law for first order kinetics is given by:

where,
k = rate constant = 
t = age of sample = ?
a = let initial amount of the reactant = 100 g
x = amount decayed = 75 g
a - x = amount left after decay process = 100 - 75 = 25g
Now put all the given values in above equation, we get


it will take john 3 hours to reach his destination
1 hour = 52 miles x 3 = 156 miles
Energy is stored in chemical bonds during photosynthesis.
During photosynthesis, the radiant energy from the sun is converted to chemical energy in carbohydrates.
Inorganic materials in the form of carbon dioxide and oxygen combine to form carbohydrates in the presence of radiant energy according to the equation below:

The energy is thus, stored in chemical bonds in the carbohydrate and this is what is oxidized during respiration to release the locked energy.
More on photosynthesis can be found here: brainly.com/question/1388366