Answer:
<h2>2.408 × 10²¹ is the correct answer!!</h2>
Balancing of chemical equation is essential because of the law of conservation of mass, which states that the mass of a system can not be created or removed.
The second equation is balanced
This is because the number of elements of each atom in the product side equal the number of elements of each atom on the reactant side.
The first equation is not balanced

This is because there is 1 molecule of
on reactant side as compared to 3 molecules of 
To balance the equation we add a coefficient of 3 on sulphuric acid (
) and a coefficient of 3 on hydrogen (
)

B, because water is changing its state from solid to liquid (it's fusion in portuguese, don't know in english), so while it's changing, water has 2 states at the same time.
It’s option B 0.0821L.atm/mol.K