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belka [17]
3 years ago
7

A chemist must dilute 34.3mL of 1.72mM aqueous calcium sulfate solution until the concentration falls to 1.00mM. He'll do this b

y adding distilled water to the solution until it reaches a certain final volume.
Calculate this final volume, in milliliters. Round your answer to 3 significant digits.
Chemistry
1 answer:
EastWind [94]3 years ago
4 0

Answer:

58.9mL

Explanation:

Given parameters:

Initial volume  = 34.3mL    = 0.0343dm³

Initial concentration  = 1.72mM   = 1.72 x 10⁻³moldm⁻³

Final concentration  = 1.00mM = 1 x 10⁻³ moldm⁻³

Unknown:

Final volume  =?

Solution:

Often times, the concentration of a standard solution may have to be diluted to a lower one by adding distilled water. To find the find the final volume, we must recognize that the number of moles of the substance in initial and final solutions are the same.

   Therefore;

              C₁V₁  =  C₂V₂

where C and V are concentration and 1 and 2 are initial and final states.

        now input the variables;

                      1.72 x 10⁻³ x  0.0343 = 1 x 10⁻³  x V₂

                        V₂ = 0.0589dm³ = 58.9mL

         

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Calculate E ° for the half‑reaction, AgCl ( s ) + e − − ⇀ ↽ − Ag ( s ) + Cl − ( aq ) given that the solubility product constant
antoniya [11.8K]

Answer: The value of E^{o} for the half-cell reaction is 0.222 V.

Explanation:

Equation for solubility equilibrium is as follows.

          AgCl(s) \rightleftharpoons Ag^{+}(aq) + Cl^{-}(aq)

Its solubility product will be as follows.

       K_{sp} = [Ag^{+}][Cl^{-}]

Cell reaction for this equation is as follows.

     Ag(s)| AgCl(s)|Cl^{-}(0.1 M)|| Ag^{+}(1.0 M)| Ag(s)

Reduction half-reaction: Ag^{+} + 1e^{-} \rightarrow Ag(s),  E^{o}_{Ag^{+}/Ag} = 0.799 V

Oxidation half-reaction: Ag(s) + Cl^{-}(aq) \rightarrow AgCl(s) + 1e^{-},   E^{o}_{AgCl/Ag} = ?

Cell reaction: Ag^{+}(aq) + Cl^{-}(aq) \rightarrow AgCl(s)

So, for this cell reaction the number of moles of electrons transferred are n = 1.

    Solubility product, K_{sp} = [Ag^{+}][Cl^{-}]

                                               = 1.77 \times 10^{-10}

Therefore, according to the Nernst equation

           E_{cell} = E^{o}_{cell} - \frac{0.0592 V}{n} log \frac{[AgCl]}{[Ag^{+}][Cl^{-}]}

At equilibrium, E_{cell} = 0.00 V

Putting the given values into the above formula as follows.

         E_{cell} = E^{o}_{cell} - \frac{0.0592 V}{n} log \frac{[AgCl]}{[Ag^{+}][Cl^{-}]}

        0.00 = E^{o}_{cell} - \frac{0.0592 V}{1} log \frac{1}{[Ag^{+}][Cl^{-}]}    

       E^{o}_{cell} = \frac{0.0592}{1} log \frac{1}{K_{sp}}

                  = 0.0591 V \times log \frac{1}{1.77 \times 10^{-10}}

                  = 0.577 V

Hence, we will calculate the standard cell potential as follows.

           E^{o}_{cell} = E^{o}_{cathode} - E^{o}_{anode}

       0.577 V = E^{o}_{Ag^{+}/Ag} - E^{o}_{AgCl/Ag}

       0.577 V = 0.799 V - E^{o}_{AgCl/Ag}

       E^{o}_{AgCl/Ag} = 0.222 V

Thus, we can conclude that value of E^{o} for the half-cell reaction is 0.222 V.

3 0
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