They separate because of different densities.
Owing to the arrangement of ions in NaCl, the structure has a high melting point and crystalline structure.
Ionic compounds are know to have a crystalline structure. This is because the ions in the compound are arranged into a crystal lattice. A crystal lattice gives a regular repeating structure of ions in the crystal.
As a result of this order in the crystal, the resultant sodium chloride structure has a high melting point and crystalline structure.
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