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pochemuha
4 years ago
12

The mass spectrum represented above is most consistent with which of the following elements? Eu Gd Tb Dy

Chemistry
1 answer:
Kryger [21]4 years ago
3 0

Answer:

The mass spectroscopy is most consistent with the element Gd

Explanation:

Here we have the average atomic mass given by the weighted average found by multiplying the abundance in nature of the various isotopes by their observed atomic masses followed by the summation of the multiplication results as follows;

Based on approximate measurement of the chart, we have the values for the relative abundance given as follows;

Isotope, I                     Relative abundance, A                       I×A                      

154                                 1                                                         154

155                                 6                                                        930

156                                 8                                                        1248

157                                 6.2                                                     973.4

158                                 10                                                       1580

160                                 8.5                                                     1360

Sum                               39.7                                                    6245.5

Average atomic mass = 6245.5/39.7 = 157.314 atomic mass unit

Atomic mass of Eu = 151.964 u

Atomic mass of Gd = 157.25 u

Atomic mass of Tb = 158.92535 u

Atomic mass of Dy = 162.5 u

Therefore, the mass spectroscopy is most consistent with the element Gd.

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Calculate the mass of methane that must be burned to provide enough heat to convert 242.0 g of water at 26.0°C into steam at 101
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<u>Answer:</u> The mass of methane burned is 12.4 grams.

<u>Explanation:</u>

The chemical equation for the combustion of methane follows:

CH_4(g)+2O_2(g)\rightarrow CO_2(g)+2H_2O(g)

The equation for the enthalpy change of the above reaction is:

\Delta H^o_{rxn}=[(1\times \Delta H^o_f_{(CO_2(g))})+(2\times \Delta H^o_f_{(H_2O(g))})]-[(1\times \Delta H^o_f_{(CH_4(g))})+(2\times \Delta H^o_f_{(O_2(g))})]

We are given:

\Delta H^o_f_{(H_2O(g))}=-241.82kJ/mol\\\Delta H^o_f_{(CO_2(g))}=-393.51kJ/mol\\\Delta H^o_f_{(CH_4(g))}=-74.81kJ/mol\\\Delta H^o_f_{O_2}=0kJ/mol

Putting values in above equation, we get:

\Delta H^o_{rxn}=[(1\times (-393.51))+(2\times (-241.82))]-[(1\times (-74.81))+(2\times (0))]\\\\\Delta H^o_{rxn}=-802.34kJ

The heat calculated above is the heat released for 1 mole of methane.

The process involved in this problem are:

(1):H_2O(l)(26^oC)\rightarrow H_2O(l)(100^oC)\\\\(2):H_2O(l)(100^oC)\rightarrow H_2O(g)(100^oC)\\\\(3):H_2O(g)(100^oC)\rightarrow H_2O(g)(101^oC)

Now, we calculate the amount of heat released or absorbed in all the processes.

  • <u>For process 1:</u>

q_1=mC_p,l\times (T_2-T_1)

where,

q_1 = amount of heat absorbed = ?

m = mass of water = 242.0 g

C_{p,l} = specific heat of water = 4.18 J/g°C

T_2 = final temperature = 100^oC

T_1 = initial temperature = 26^oC

Putting all the values in above equation, we get:

q_1=242.0g\times 4.18J/g^oC\times (100-(26))^oC=74855.44J

  • <u>For process 2:</u>

q_2=m\times L_v

where,

q_2 = amount of heat absorbed = ?

m = mass of water or steam = 242 g

L_v = latent heat of vaporization = 2257 J/g

Putting all the values in above equation, we get:

q_2=242g\times 2257J/g=546194J

  • <u>For process 3:</u>

q_3=mC_p,g\times (T_2-T_1)

where,

q_3 = amount of heat absorbed = ?

m = mass of steam = 242.0 g

C_{p,g} = specific heat of steam = 2.08 J/g°C

T_2 = final temperature = 101^oC

T_1 = initial temperature = 100^oC

Putting all the values in above equation, we get:

q_3=242.0g\times 2.08J/g^oC\times (101-(100))^oC=503.36J

Total heat required = q_1+q_2+q_3=(74855.44+546194+503.36)=621552.8J=621.552kJ

  • To calculate the number of moles of methane, we apply unitary method:

When 802.34 kJ of heat is needed, the amount of methane combusted is 1 mole

So, when 621.552 kJ of heat is needed, the amount of methane combusted will be = \frac{1}{802.34}\times 621.552=0.775mol

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

Molar mass of methane = 16 g/mol

Moles of methane = 0.775 moles

Putting values in above equation, we get:

0.775mol=\frac{\text{Mass of methane}}{16g/mol}\\\\\text{Mass of methane}=(0.775mol\times 16g/mol)=12.4g

Hence, the mass of methane burned is 12.4 grams.

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