Increasing the cell's volume would reduce the efficiency of the diffusion of materials through the plasma membrane into the cytoplasm of the cell.
On the other hand, increase the surface area and decreasing the volume oft the cell would increase the rate of diffusion across the plasma membrane.
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The very function, or job of CELL MEMBRANES is to protect the cell from it's surroundings, or in other words, to keep it safe. It controls the movement of substances in and out of cells and organelles, like a guard watching for suspicious activity and protecting something.
The cell membrane itself is a thin, flexible layer around the cells of all living things. It separates the inside of the cells from the outside of the cells.