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Setler79 [48]
3 years ago
10

For metallic structures, does the packing efficiency (see sample exercise 12.1 in textbook) increase or decrease as the number o

f nearest neighbors (the coordination number) decreases?
Chemistry
1 answer:
qaws [65]3 years ago
5 0
Metallic solids or metallic structures experience metallic bonds which are the forces of attractions between the sea of electrons and the nucleus of the metallic atoms. They share a network of highly delocalized electrons.
I therefore think that the packing efficiency decreases as the number of nearest neighbors decreases.
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The vapor pressure of water at 25.0°c is 23.8 torr. determine the mass of glucose (molar mass = 180 g/mol) needed to add to 500.
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Q: A
according to this formula, we can get the mole fraction of water (n):
P(solu) = n Pv(water)
when we have Pv(solu) = 22.8 and Pv(water) = 23.8 so by substitution:
22.8 = n * 23.8
n= 0.958
- we need to get the moles of glucose:
moles of water = 500 g(mass weight) / 18 (molar weight)= 27.7 mol
n = moles of water / ( moles of water + moles of glucose)
0.958   = 27.7 / ( 27.7+ moles of glucose)
0.958 moles of glucose + 26.5 = 27.7
0.968 moles of glucose = 1.2
moles of glucose = 1.253 mol
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                                      = 1.253 x 180 = 225.5 g
Q: B
here we also need to get n (mole fraction of water )by using this formula:
Pv(solu) = n Pv(water)
when we have Pv(solu)=132 & Pv(water)=150 so, by substition:
132= n * 150
n = 0.88
so, mole fraction of solution = 1 - 0.88 = 0.12
and we can get after that the moles of water = (mass weight / molar mass)
- no.moles of water = 85 g / 18 g/mol = 4.7 moles
- total moles in solution = moles of water / moles fraction of water 
                                        = 4.7 / 0.88 = 5.34 moles 
∴ moles of the solution = total moles in solu - moles of water 
                                       = 5.34 - 4.7 = 0.64 moles solute
∴ the molar mass of the solute = mass weight of solute / no.of moles of solute
                                                    = 53.8 / 0.64 = 84 g/mole

Q: C

moles of urea (NH2)2 CO = mass weight / molar mass
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moles of methanol = mass weight / molar mass 
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moles fraction of methanol = moles of methanol / (moles of methanol + moles of urea )
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by substitution in Pv formula we will be able to get the vapour pressure of the solu :
Pv(solu) = n P°v
Pv(solu) = 0.95 * 89 mm Hg 
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