Answer: The molar enthalpy change is 73.04 kJ/mol
Explanation:
moles of HCl=
As NaOH is in excess 0.0415 moles of HCl reacts with 0.0415 moles of NaOH.
volume of water = 100.0 ml + 50.0 ml = 150.0 ml
density of water = 1.0 g/ml
mass of water =
q = heat released
m = mass = 150.0 g
c = specific heat =
= change in temperature =
Thus 0.0415 mol of HCl produces heat = 3031.3 J
1 mol of HCL produces heat =
Thus molar enthalpy change is 73.04 kJ/mol
Answer : The value of equilibrium constant for this reaction at 262.0 K is
Explanation :
As we know that,
where,
= standard Gibbs free energy = ?
= standard enthalpy = -45.6 kJ = -45600 J
= standard entropy = -125.7 J/K
T = temperature of reaction = 262.0 K
Now put all the given values in the above formula, we get:
The relation between the equilibrium constant and standard Gibbs free energy is:
where,
= standard Gibbs free energy = -12666.6 J
R = gas constant = 8.314 J/K.mol
T = temperature = 262.0 K
K = equilibrium constant = ?
Now put all the given values in the above formula, we get:
Therefore, the value of equilibrium constant for this reaction at 262.0 K is