Reading the Temperature of Thermometers
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The allowable combination for the atomic orbital is n=4, l=2, =2.
Three quantum numbers specify an atomic orbital:
- The principal quantum number, n, which is a positive integer, describes the relative size of the orbital and its distance from the nucleus.
- l is the angular momentum quantum number that is related to the shape of the orbital; l is an integer from 0 to n-1 (so n limits l ),
- is the magnetic quantum number that prescribes the three-dimensional shape of the orbital around the nucleus;
values are integers from -l to =l(l limits ml)
For n = 4, l can four values: 0, 1, 2, and 3. To be consistent with =+2the l value must be higher than 1. There are two l values that are consistent with n and
values: l= 2 or 3
Therefore, the allowable condition is n=4, l=2, =2
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When the molecule undergoes chlorination with Cl2 on heating, the hydrogen atom of the alkyl group is replaced by the chlorine atom and form chloroalkanes. The molecule X containes three types of alkyl halides, therefore three different types of chloroalkanes are formed by the replacement of hydrogem atom linked to these alkyl groups. Thus the three different types of chloroalkanes are formed - primary, secondary, and thertiary chloroalkane. Chlorination is not selective so a mixture pf products results. The products formed by the reaction of the molecule with Y with Cl2 are shown on the attached file.
The Newman projection gives the view of the molecule. In molecule A the torsional strain and in B steric strain are present because of the gauche methyl group.
<h3>What is a torsional strain?</h3>The Newman projection depicts the molecules in the head-on view and uses the letters and the lines to represent the molecule. The torsional strain is because of the molecule's resistance to the twisting.
The steric strain is the Vander wall strain that is due to the forced interaction of the molecules separated by covalent bonds resulting in molecular potential energy.
The diagram for the question is attached below.
Therefore, the correct blanks are <u>torsional</u>, <u>steric</u>, and <u>gauche</u>.
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