LMBO, for science.
Answer:
<em>The increase in kinetic energy leads to leakage of water from the syringe. When the outside temperature is more than the liquid temperature, say the syringe is out in sunshine, then the liquid becomes slightly warmer.</em>
Answer : The rate of change of the total pressure of the vessel is, 10.5 torr/min.
Explanation : Given,
=21 torr/min
The balanced chemical reaction is,

The rate of disappearance of
= ![-\frac{1}{2}\frac{d[NO]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BNO%5D%7D%7Bdt%7D)
The rate of disappearance of
= ![-\frac{d[Cl_2]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7Bd%5BCl_2%5D%7D%7Bdt%7D)
The rate of formation of
= ![\frac{1}{2}\frac{d[NOCl]}{dt}](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BNOCl%5D%7D%7Bdt%7D)
As we know that,
=21 torr/min
So,
![-\frac{d[Cl_2]}{dt}=-\frac{1}{2}\frac{d[NO]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7Bd%5BCl_2%5D%7D%7Bdt%7D%3D-%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BNO%5D%7D%7Bdt%7D)
![\frac{d[Cl_2]}{dt}=\frac{1}{2}\times 21torr/min=10.5torr/min](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BCl_2%5D%7D%7Bdt%7D%3D%5Cfrac%7B1%7D%7B2%7D%5Ctimes%2021torr%2Fmin%3D10.5torr%2Fmin)
And,
![\frac{1}{2}\frac{d[NOCl]}{dt}=\frac{1}{2}\frac{d[NO]}](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BNOCl%5D%7D%7Bdt%7D%3D%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BNO%5D%7D)
![\frac{d[NOCl]}{dt}=\frac{d[NO]}=21torr/min](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BNOCl%5D%7D%7Bdt%7D%3D%5Cfrac%7Bd%5BNO%5D%7D%3D21torr%2Fmin)
Now we have to calculate the rate change.
Rate change = Reactant rate - Product rate
Rate change = (21 + 10.5) - 21 = 10.5 torr/min
Therefore, the rate of change of the total pressure of the vessel is, 10.5 torr/min.
How likely and forcefully a substance reacts with oxygen, water, acids and other salts