Answer:
Hg∧2+ has a negative standard entropy because the ions are highly solvated in aqueous phase; smaller the ionic size, the more highly it is surrounded by solvated ions. Therefore it will be in highly ordered state hence the entropy decreases.
Hg2 ^2+ has a positive standard entropy because the ionic size of Hg^2+ is smaller than Hg2 ^2+, so therefore the Hg^2+ is highly solvated and that means that it is in highly ordered state. Hg2 ^2+ is not highly solvated so it will have a positive entropy
Explanation:
The values of standard entropy of aqueous ions has a negative standard entropy because the ions are highly solvated in aqueous phase; smaller the ionic size, the more highly it is surrounded by solvated ions. Therefore it will be in highly ordered state hence the entropy decreases.
Hg2 ^2+ has a positive standard entropy because the ionic size of Hg^2+ is smaller than Hg2 ^2+, so therefore the Hg^2+ is highly solvated and that means that it is in highly ordered state. Hg2 ^2+ is not highly solvated so it will have a positive entropy
