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ddd [48]
4 years ago
8

A silver block, initially at 59.4 °C, is submerged into 100.0 g of water at 24.8 °C, in an insulated container. The final temper

ature of the mixture upon reaching thermal equilibrium is 26.2 °C.
What is the mass of the silver block?
Chemistry
1 answer:
Tatiana [17]4 years ago
4 0

Answer:

The mass of silver block = 73.95 g

Explanation:

Given,

For water:

Mass = 100.0 g

Initial temperature = 24.8 °C

Final temperature = 26.2 °C

Specific heat of water = 4.184 J/g°C

For silver:

Mass = x g

Initial temperature = 59.4 °C

Final temperature = 26.2 °C

Specific heat of water = 0.2386 J/g°C

Heat gain by water = Heat lost by silver

Thus,  

m_{water}\times C_{water}\times (T_f-T_i)=-m_{silver}\times C_{silver}\times (T_f-T_i)

Where, negative sign signifies heat loss

Or,  

m_{water}\times C_{water}\times (T_f-T_i)=m_{silver}\times C_{silver}\times (T_i-T_f)

So,  100.0\times 4.184\times (26.2-24.8)=x\times 0.2386\times (59.4-26.2)

x\times \:0.2386\left(59.4-26.2\right)=100\times \:4.184\left(26.2-24.8\right)

x\times \:0.2386\left(59.4-26.2\right)=585.76

x=\frac{585.76}{7.92152}

x=73.95

<u>Hence, the mass of silver block = 73.95 g</u>

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a 25 ml volume of a sodium hydroxide solution requires 19.6 mL of a 0.189 M HCl acid for neutralization. A 10 mL volume of phosp
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Answer: 0.172 M

Explanation:

a) To calculate theconcentration of base, we use the equation given by neutralization reaction:

n_1M_1V_1=n_2M_2V_2

where,

n_1,M_1\text{ and }V_1 are the n-factor, molarity and volume of acid which is HCl

n_2,M_2\text{ and }V_2 are the n-factor, molarity and volume of base which is NaOH.

We are given:

n_1=1\\M_1=0.189M\\V_1=19.6mL\\n_2=1\\M_2=?\\V_2=25mL

Putting values in above equation, we get:

1\times 0.189\times 19.6=1\times M_2\times 25\\\\M_2=0.148

b) To calculate the concentration of acid, we use the equation given by neutralization reaction:

n_1M_1V_1=n_2M_2V_2

where,

n_1,M_1\text{ and }V_1 are the n-factor, molarity and volume of acid which is H_3PO_4

n_2,M_2\text{ and }V_2 are the n-factor, molarity and volume of base which is NaOH.

We are given:

n_1=3\\M_1=?\\V_1=10mL\\n_2=1\\M_2=0.148\\V_2=34.9mL

Putting values in above equation, we get:

3\times M_1\times 10=1\times 0.148\times 34.9\\\\M_1=0.172M

The concentration of the phosphoric acid solution is 1.172 M

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Mass per mol = 2/2*molar mass of HCl = 2/ (2*36.46) = 0.0274 g/mol
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