Answer:
The equilibrium pressure of NO2 is 0.084 atm
Explanation:
Step 1: Data given
A reaction mixture initially contains 0.86 atm NO and 0.86 atm SO3.
Kp = 0.0118
Step 2: The balanced equation
NO( g) + SO3( g) ⇌ NO2( g) + SO2( g)
Step 3: The initial pressures
p(NO) = 0.86 atm
p(SO3) = 0.86 atm
p(NO2) = 0 atm
p(SO2) = 0 atm
Step 4: The pressure at the equilibrium
For 1 mol NO we need 1 mol SO3 to produce 1 mol NO2 and 1 mol SO2
p(NO) = 0.86 -x atm
p(SO3) = 0.86 -xatm
p(NO2) = x atm
p(SO2) = x atm
Step 5: Define Kp
Kp = ((pNO2)*(pSO2)) / ((pNO)*(pSO3))
Kp = 0.0118 = x²/(0.86 - x)²
X = 0.08427
p(NO) = 0.86 -0.08427 = 0.77573 atm
p(SO3) = 0.86 -0.08427 = 0.77573 atm
p(NO2) = 0.08427 atm
p(SO2) = 0.08427 atm
The equilibrium pressure of NO2 is 0.08427 atm ≈ 0.084 atm
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Equilibrium occurs when the rate of the forward reaction is the same as the rate of the reverse reaction. This doesn't necessarily mean the concentrations or pressure are the same on both sides of the equation, only the rates are the same
Explanation:
As you move across the periodic table, the number of protons and neutrons increases but the number of orbital levels of the period remains the same. The atomic radii therefore decrease, across the period, because the increase in proton number causes an increased pull of the orbital electrons bringing them closer to the nucleus.
As you move down a group in a periodic table, the number of orbital levels increase. The effective nuclear charge of the nucleus of the atoms decreases due to the increased number of orbital levels that shield the valence electrons from the attractive force nucleus.