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jeyben [28]
4 years ago
10

1. For dry air at 1.0000 atm pressure, the densities at –50°C, 0°C, and 69°C are 1.5826 g dm–3 , 1.2929 g dm–3, and 1.0322 g dm–

3, respectively. a) Assume a sample of mass 1000 g, and calculate the volume at each temperature. b) From these data, and assuming that air obeys Charles’s law, determine a value for th
Chemistry
1 answer:
pshichka [43]4 years ago
8 0

Answer :

(a) The value of volume of air at temperature -50^oC,0^oC\text{ and }69^oC are 631.87dm^3,773.46dm^3\text{ and }968.80dm^3 respectively.

Explanation :

(a) The formula used for density is:

Density=\frac{Mass}{Volume}

or,

Volume=\frac{Mass}{Density}

Now we have to calculate the volume at each temperature.

The mass of sample = 1000 g

<u>At temperature -50^oC :</u>

Density = 1.5826g/dm^3

Volume=\frac{1000g}{1.5826g/dm^3}=631.87dm^3

<u>At temperature 0^oC :</u>

Density = 1.2929g/dm^3

Volume=\frac{1000g}{1.2929g/dm^3}=773.46dm^3

<u>At temperature 69^oC :</u>

Density = 1.0322g/dm^3

Volume=\frac{1000g}{1.0322g/dm^3}=968.80dm^3

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Explanation:

The given data is as follows.

     Vapour pressure of pure CCl_{4} = 33.85 Torr

         Temperature = 298 K

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Therefore, calculate the vapor pressure of Br_{2} as follows.      

     Vapour pressure of Br_{2} = mole fraction of Br_{2} x K of Br_{2}

                                    = 0.050 x 122.36 Torr

                                   = 6.118 Torr

So, vapor pressure of Br_{2} is 6.118 Torr .

Now, calculate the vapor pressure of carbon tetrachloride as follows.

     Vapour pressure of CCl_{4} = mole fraction of CCl_{4} x Pressure of CCl_{4}

                                     = (1 - 0.050) × 33.85 Torr

                                     = 32.1575 Torr

So, vapor pressure of CCl_{4} is 32.1575 Torr  .

Hence, the total pressure will be as follows.

                         = 6.118 Torr + 32.1575 Torr

                         = 38.2755 Torr

Therefore, composition of CCl_{4} = \frac{32.1575 Torr}{38.2755 Torr}

                         = 0.8405

Composition of CCl_{4} is 0.8405 .

And, composition of Br_{2} = \frac{6.118 Torr}{38.2755 Torr}

                                                  = 0.1598

Composition of Br_{2} is 0.1598 .

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