D: they have new dna combinations
Compounds Na₂SO₄ and NaCl are mixed together are we are asked to find the concentration of Na⁺ in the mixture
Na₂SO₄ ---> 2 Na⁺ + SO₄³⁻
1 mol of Na₂SO₄ gives out 2 mol of Na⁺ ions
the number of Na₂SO₄ moles added - 0.800 M/1000 * 100 ml
= 0.08 mol
therefore number of Na⁺ ions from Na₂SO₄ = 0.08 * 2 = 0.16 mol
NaCl ----> Na⁺ + Cl⁻
1 mol of NaCl gives 1 mol of Na⁺ ions
number of NaCl moles added = 1.20 M/1000 * 200 ml
= 0.24 mol
number of Na⁺ ions from NaCl = 0.24 mol
total number of Na⁺ ions in the mixture = 0.16 mol + 0.24 mol = 0.4 mol
as stated the volumes are additive,
therefore total volume = 100 ml + 200 ml = 300 ml
the concentration of Na⁺ ions = number of moles / volume
= 0.4 mol/ 0.3 dm³
concentration of Na⁺ = 1.33 mol/dm³
Answer:
a. 1.7 × 10⁻⁴ mol·L⁻¹; b. 5.5 × 10⁻⁹ mol·L⁻¹
c. 2.3 × 10⁻⁴ mol·L⁻¹; 5.5 × 10⁻⁸ mol·L⁻¹
Explanation:
a. Silver iodate
Let s = the molar solubility.
AgIO₃(s) ⇌ Ag⁺(aq) + IO₃⁻(aq); Ksp = 3.0 × 10⁻⁸
E/mol·L⁻¹: s s
b. Barium sulfate
BaSO₄(s) ⇌ Ba²⁺(aq) + SO₄²⁻(aq); Ksp = 1.1 × 10⁻¹⁰
I/mol·L⁻¹: 0.02 0
C/mol·L⁻¹: +s +s
E/mol·L⁻¹: 0.02 + s s
c. Using ionic strength and activities
(i) Calculate the ionic strength of 0.02 mol·L⁻¹ Ba(NO₃)₂
The formula for ionic strength is
(ii) Silver iodate
a. Calculate the activity coefficients of the ions
b. Calculate the solubility
AgIO₃(s) ⇌ Ag⁺(aq) + IO₃⁻(aq)
(iii) Barium sulfate
a. Calculate the activity coefficients of the ions
b. Calculate the solubility
BaSO₄(s) ⇌ Ba²⁺(aq) + SO₄²⁻(aq