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vaieri [72.5K]
3 years ago
12

Calculate the standard molar enthalpy for the complete combustion of liquid ethanol (c2h5oh) using the standard enthalpies of fo

rmation of the reactants and products.
Chemistry
2 answers:
Naddik [55]3 years ago
7 0

The standard molar enthalpy for the complete combustion of liquid ethanol (C₂H₅OH) : <u>-1366.7 kJ  mol⁻¹</u>

<h3>Further explanation</h3>

The change in enthalpy in the formation of 1 mole of the elements is called enthalpy of formation

The enthalpy of formation measured in standard conditions (25 ° C, 1 atm) is called the standard enthalpy of formation (ΔHf °)

Determination of the enthalpy of formation of a reaction can be through a calorimetric experiment, based on the principle of Hess's Law, enthalpy of formation table, or from bond energy data

Delta H reaction (ΔH) is the amount of heat / heat change between the system and its environment

(ΔH) can be positive (endothermic = requires heat) or negative (exothermic = releasing heat)

The value of ° H ° can be calculated from the change in enthalpy of standard formation:

∆H ° rxn = ∑n ∆Hf ° (product) - ∑n ∆Hf ° (reactants)

We complete the data values ​​for ∆Hf° of compounds

∆H ° f C₂H₅OH (ℓ): -277.7 kJ /mol

∆H ° f 2CO₂ (g): -393.5 kJ /mol

∆H ° f H₂O (g): -285.8 kJ /mol

°H ° f 3O₂ (g): 0 (ΔHf ° (O₂ (g)) is zero for free elements)

Combustion reaction that occurs  :

C₂H₅OH (ℓ) + 3O₂ (g) -> 2CO₂ (g) + 3H₂O (g)

then :

ΔHrxn ° = (2ΔHf ° (CO₂ (g) + 3ΔHf ° (H₂O (l)) - (ΔHf ° (C₂H₅OH (l)) + 3ΔHf ° (O₂ (g))

ΔHrxn ° = [(2 × -393.5 + 3 × -285.8) - (-277.7 + 0)] kJ mol⁻¹

ΔHrxn ° = -1366.7 kJ  mol⁻¹

<h3>Learn more </h3>

Delta H solution

brainly.com/question/10600048

an exothermic reaction

brainly.com/question/1831525

as endothermic or exothermic

brainly.com/question/11419458

an exothermic dissolving process

brainly.com/question/10541336

Keywords: Delta H reaction (ΔH), enthalpy of standard formation

olga2289 [7]3 years ago
6 0
Answer : To calculate the standard molar enthalpy of complete combustion of liquid ethanol can be done by using the formula given below;

C_{2}  H_{5}OH + 3O_{2} ----\ \textgreater \   2CO_{2}  + 3 H_{2}O

Now, the enthalpies of the elements in their standard state is zero always. 

So the H_{reaction} =  H_{products}  - H_{reactants}

Here we can avoid the heat of enthalpy of oxygen,carbon dioxide and water as they exists in their standard states.

So the H_{reaction} = H_{ C_{2}H_{5}OH}
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