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Nonamiya [84]
3 years ago
9

A 400 mL sample of hydrogen gas is collected over water at 20°C and 760 torr the vapor pressure of water at 20°C is 17.5 torr. w

hat volume will the dry hydrogen gas occupy at 20°C and 760 torr?
Chemistry
1 answer:
o-na [289]3 years ago
4 0

Answer:

V2 = 17371.43ml

Explanation:

We use Boyles laws

since temperature is constant

P1V1=P2V2

760 x 400 = 17.5 x V2

304000 = 17.5 x V2

V2 = 304000/17.5

V2 = 17371.43ml

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A solution contains 3.1 mM Zn(NO3)2 and 4.2 mM Ca(NO3)2. The p-function for Zn2+ is _____, and the p-function for NO3- is _____.
seropon [69]

<u>Answer:</u> The p-function of Zn^{2+} and NO_3^{-} ions are 2.51 and 2.14 respectively.

<u>Explanation:</u>

p-function is defined as the negative logarithm of any concentration.

We are given:

Millimolar concentration of zinc nitrate = 3.1 mM

Millimolar concentration of calcium nitrate = 4.2 mM

Converting this into molar concentration, we use the conversion factor:

1 M = 1000 mM

  • Concentration of zinc nitrate = 0.0031 M = 0.0031 mol/L

1 mole of zinc nitrate produces 1 mole of zinc ions and 2 moles of nitrate ions

Concentration of zinc ions = 0.0031 M

Concentration of nitrate ions in zinc nitrate, M_1=(2\times 0.0031)=0.0062M

  • Concentration of calcium nitrate = 0.0042 M = 0.0042 mol/L

1 mole of calcium nitrate produces 1 mole of calcium ions and 2 moles of nitrate ions

Concentration of calcium ions = 0.0042 M

Concentration of nitrate ions in calcium nitrate, M_2=(2\times 0.0042)=0.0084M

To calculate the concentration of nitrate ions in the solution, we use the equation:

M=\frac{M_1V_1+M_2V_2}{V_1+V_2}

Putting values in above equation, we get:

M=\frac{(0.0062\times 1)+(0.0084\times 1)}{1+1}\\\\M=0.0073M

Calculating the p-function of zinc ions and nitrate ions in the solution:

  • <u>For zinc ions:</u>

\text{p-function of }Zn^{2+}\text{ ions}=-\log[Zn^{2+}]

\text{p-function of }Zn^{2+}\text{ ions}=-\log(0.0031)\\\\\text{p-function of }Zn^{2+}\text{ ions}=2.51

  • <u>For nitrate ions:</u>

\text{p-function of }NO_3^{-}\text{ ions}=-\log[NO_3^{-}]

\text{p-function of }NO_3^{-}\text{ ions}=-\log(0.0073)\\\\\text{p-function of }NO_3^{-}\text{ ions}=2.14

Hence, the p-function of Zn^{2+} and NO_3^{-} ions are 2.51 and 2.14 respectively.

5 0
3 years ago
A 1.0-L buffer solution is 0.10 M in HF and 0.050 M in NaF. Which action destroys the buffer? (a) adding 0.050 mol of HCl (b) ad
Volgvan

Answer:

(a) adding 0.050 mol of HCl

Explanation:

A buffer is defined as the mixture of a weak acid and its conjugate base -or vice versa-.

In the buffer:

1.0L × (0.10 mol / L) = 0.10 moles of HF -<em>Weak acid-</em>

1.0L × (0.050 mol / L) = 0.050 moles of NaF -<em>Conjugate base-</em>

-The weak acid reacts with bases as NaOH and the conjugate base reacts with acids as HCl-

Thus:

<em>(a) adding 0.050 mol of HCl:</em> The addition of 0.050moles of HCl produce the reaction of 0.050 moles of NaF producing HF. That means after the reaction, all NaF is consumed and you will have in solution just the weak acid <em>destroying the buffer</em>.

(b) adding 0.050 mol of NaOH: The NaOH reacts with HF producing more NaF. Would be consumed just 0.050 moles of HF -remaining 0.050 moles of HF-. Thus, the buffer <em>wouldn't be destroyed</em>.

(c) adding 0.050 mol of NaF: The addition of conjugate base <em>doesn't destroy the buffer</em>

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