Answer:
The precipitate is CuS.
Sulfide will precipitate at [S2-]= 3.61*10^-35 M
Explanation:
<u>Step 1: </u>Data given
The solution contains 0.036 M Cu2+ and 0.044 M Fe2+
Ksp (CuS) = 1.3 × 10-36
Ksp (FeS) = 6.3 × 10-18
Step 2: Calculate precipitate
CuS → Cu^2+ + S^2- Ksp= 1.3*10^-36
FeS → Fe^2+ + S^2- Ksp= 6.3*10^-18
Calculate the minimum of amount needed to form precipitates:
Q=Ksp
<u>For copper</u> we have: Ksp=[Cu2+]*[S2-]
Ksp (CuS) = 1.3*10^-36 = 0.036M *[S2-]
[S2-]= 3.61*10^-35 M
<u>For Iron</u> we have: Ksp=[Fe2+]*[S2-]
Ksp(FeS) = 6.3*10^-18 = 0.044M*[S2-]
[S2-]= 1.43*10^-16 M
CuS will form precipitates before FeS., because only 3.61*10^-35 M Sulfur Ions are needed for CuS. For FeS we need 1.43*10^-16 M Sulfur Ions which is much larger.
The precipitate is CuS.
Sulfide will precipitate at [S2-]= 3.61*10^-35 M
The change of the statue of liberty from copper to green is an example of a chemical change.
<h3>Physical and chemical change</h3>
A physical change does not involve the formation of new substances and the composition of the substance does not change. However, in a chemical change, a new substance is formed and the composition of the substance changes.
The statement that reflect a chemical change is;
- The Statue of Liberty’s metal tarnishes from copper to green.
Learn more about physical and chemical change: brainly.com/question/13316655
A physical change is any change in a substances form that does not change its chemical makeup. Examples of physical changes are breaking a stick or melting ice. A chemical change occurs when atoms of a substance are rearranged, and the bonds between the atoms are broken or formed. HOPE THIS HELPS!!
The question is incomplete.
You need two additional data:
1) the original volume
2) what solution you added to change the volume.
This is a molarity problem, so remember molarity definition and formula:
M = n / V in liters: number of moles per liter of solution
To give you the key to answer this kind of questions, supppose the original volumen was 1 ml and that you added only water (solvent).
The original solution was:
V= 1 ml
M = 0.2 M
Using the formula for molarity, M = n / V
n = M×V = 0.2 M × (1 / 10000)l = 0.0002 moles
For the final solution:
n = 0.0002 moles
M = 0.04
From M = n / V ⇒ V = n / M = 0.002 moles / 0.04 M = 0.05 l
Change to ml ⇒ 0.05 l × 1000 ml / l = 50 ml. This would be the answer for the hypothetical problem that I assumed for you.
I hope this gives you all the cues you need to answer similar problems about molarity.
