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natima [27]
4 years ago
8

Sulfur dioxide has a vapor pressure of 462.7 mm Hg at –21.0 °C and a vapor pressure of 140.5 mm Hg at –44.0 °C. What is the enth

alpy of vaporization of sulfur dioxide? (R = 8.314 J/K⋅mol)
Chemistry
1 answer:
stealth61 [152]4 years ago
4 0

Answer : The value of \Delta H_{vap} is 28.97 kJ/mol

Explanation :

To calculate \Delta H_{vap} of the reaction, we use clausius claypron equation, which is:

\ln(\frac{P_2}{P_1})=\frac{\Delta H_{vap}}{R}[\frac{1}{T_1}-\frac{1}{T_2}]

where,

P_1 = vapor pressure at temperature -21.0^oC = 462.7 mmHg

P_2 = vapor pressure at temperature -44.0^oC = 140.5 mmHg

\Delta H_{vap} = Enthalpy of vaporization = ?

R = Gas constant = 8.314 J/mol K

T_1 = initial temperature = -21.0^oC=[-21.0+273]K=252K

T_2 = final temperature = 45^oC=[-41.0+273]K=232K

Putting values in above equation, we get:

\ln(\frac{140.5mmHg}{462.7mmHg})=\frac{\Delta H_{vap}}{8.314J/mol.K}[\frac{1}{252}-\frac{1}{232}]\\\\\Delta H_{vap}=28966.6J/mol=28.97kJ/mol

Therefore, the value of \Delta H_{vap} is 28.97 kJ/mol

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