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Ber [7]
3 years ago
11

For the titration of 50.0 ml of 0.020 m aqueous salicylic acid with 0.020 m koh (aq), calculate the ph after the addition of 55.

0 ml of the base. for salycylic acid, pka = 2.97.'
Chemistry
1 answer:
Reil [10]3 years ago
3 0
First by getting moles of salicylic acid:

moles of salicylic acid = molarity * volume 

                                     = 0.02 * 0.05 L

                                     = 0.001 mol

then moles of base KOH = molarity * volume 

                                           = 0.02 * 0.055L

                                           = 0.0011

when total volume = 0.05 + 0.055 = 0.105 L

[salisalic acid] = moles / total volume

                        = 0.001 / 0.105

                        = 0.0095

[KOH] = moles / total volume

           = 0.0011 / 0.105

           = 0.01

by using H-H equation, we can get the PH:

 PH = Pka + ㏒[salt/acid]

by substitution:

PH = 2.97 + ㏒[0.01 / 0.0095]

      = 2.99 
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Explanation :

First we have to calculate the heat of solution.

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\Delta T = change in temperature = 0.360 K

Now put all the given values in the above formula, we get:

q=1.28kJ/K\times 0.360K

q=0.4608kJ=460.8J

Now we have to calculate the molar heat solution of KCl.

\Delta H=\frac{q}{n}

where,

\Delta H = enthalpy change = ?

q = heat released = 460.8 J

m = mass of KCl = 2.00 g

Molar mass of KCl = 74.55 g/mol

\text{Moles of }KCl=\frac{\text{Mass of }KCl}{\text{Molar mass of }KCl}=\frac{2.00g}{74.55g/mole}=0.0268mole

Now put all the given values in the above formula, we get:

\Delta H=\frac{460.8J}{0.0268mole}

\Delta H=17194.029J/mol=17.19kJ/mol

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What is the pH of a solution made by mixing 30.00 mL 0.10 M HCl with 40.00 mL of 0.10 M KOH? Assume that the volumes of the solu
nirvana33 [79]

Answer:

pH = 12.15

Explanation:

To determine the pH of the HCl and KOH mixture, we need to know that the reaction is  a neutralization type.

HCl  +  KOH  →  H₂O  +  KCl

We need to determine the moles of each compound

M = mmol / V (mL) → 30 mL . 0.10 M = 3 mmoles of HCl

M = mmol / V (mL) → 40 mL . 0.10 M = 4 mmoles of KOH

The base is in excess, so the HCl will completely react and we would produce the same mmoles of KCl

HCl  +  KOH  →  H₂O  +  KCl

3 m       4 m                       -

             1 m                      3 m

As the KCl is a neutral salt, it does not have any effect on the pH, so the pH will be affected, by the strong base.

1 mmol of KOH has 1 mmol of OH⁻, so the [OH⁻] will be 1 mmol / Tot volume

[OH⁻] 1 mmol / 70 mL = 0.014285 M

- log [OH⁻] = 1.85 → pH = 14 - pOH → 14 - 1.85 = 12.15

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3 years ago
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