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allsm [11]
3 years ago
8

If Kp = 0.15, which statement is true of the reaction mixture before any reaction occurs?

Chemistry
1 answer:
Fiesta28 [93]3 years ago
6 0
The given sentence is part of a longer question.

I found this question with the same sentence. So, I will help you using this question:

For the reaction N2O4<span>(g) ⇄ 2NO</span>2(g), a reaction mixture at a certain temperature initially contains both N2O4 and NO2 in their standard states (meaning they are gases with a pressure of 1 atm<span>).  If </span>Kp = 0.15, which statement is true of the reaction mixture before any reaction occurs?


(a) Q = K<span>;   The reaction </span>is at equilibrium.
(b) Q < K<span>;   The reaction </span>will proceed to the right.
(c) Q > K<span>;   The reaction </span>will proceed to the left.

The answer is the option (c) Q > K<span>; The reaction will proceed to the </span>left, since Qp<span> = </span>1<span>, and 1 > 0.15.</span>
Explanation:

Kp is the equilibrium constant in term of the partial pressures of the gases.

Q is the reaction quotient. It is a measure of the progress of a chemical reaction.

The reaction quotient has the same form of the equilibrium constant but using the concentrations or partial pressures at any moment.

At equilibrium both Kp and Q are equal. Q = Kp

If Q < Kp then the reaction will go to the right (forward reaction) trying to reach the equilibrium,

If Q > Kp then the reaction will go to the left (reverse reaction) trying to reach the equilibrium.

Here, the state is that both pressures are 1 atm, so Q = (1)^2 / 1 = 1.

Since, Q = 1 and Kp = 0.15, Q > Kp and the reaction will proceed to the left.
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Gallium is produced by the electrolysis of a solution made by dissolving gallium oxide in concentrated NaOH ( aq ) . Calculate t
Sedbober [7]

Answer:

Approximately 6.30\times 10^{-3}\;\rm mol.

Explanation:

The gallium here is likely to be produced from a \rm NaGaO_2\, (aq) solution using electrolysis. However, the problem did not provide a chemical equation for that process. How many electrons will it take to produce one mole of gallium?

Note the Roman Numeral "\mathtt{(III)}" next to \rm Ga.  This numeral indicates that the oxidation state of the gallium in this solution is equal to +3. In other words, each gallium atom is three electrons short from being neutral. It would take three electrons to reduce one of these atoms to its neutral, metallic state in the form of \rm Ga\, (s).

As a result, it would take three moles of electrons to deposit one mole of gallium atoms from this gallium \mathtt{(III)} solution.

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t = \rm 80.0\; min = 80.0\; min \times 60\;s \cdot min^{-1} = 4800\; s.

Q = I \cdot t = \rm 0.380 \; A \times 4800 \; s = 1.824\times 10^3\; C.

Calculate the number of electrons in moles using the Faraday's constant. This constant gives the size of the charge (in coulombs) on each mole of electrons.

\begin{aligned} n(\text{electrons}) &= \frac{Q}{F} \cr &= \rm \dfrac{1.824\times 10^3\; C}{96485.332\; C \cdot mol^{-1}}\cr &\approx \rm 1.89\times 10^{-2}\; mol \end{aligned}.

It takes three moles of electrons to deposit one mole of gallium atoms \rm Ga\, (s). As a result, \rm 1.89\times 10^{-2}\; mol of electrons would deposit \displaystyle \rm \frac{1}{3}\times 1.89\times 10^{-2}\; mol \approx 6.30\times 10^{-3}\; mol of gallium atoms \rm Ga\, (s).

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Calcium is a metal. When metals react with non-metals, electrons are transferred from the metal atoms to the non-metal atoms forming ions. The resulting compound is known  as an ionic compound.

For example, when calcium metal reacts with chlorine gas,   calcium gives up its two valence electrons and Chlorine accepts them resulting in a new substance called calcium chloride in which the two elements have ended up forming ionic bonds.

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