Ksp of PbBr₂ is 6.60 × 10⁻⁶. The molar solubility of PbBr₂ in pure water is 0.0118M.
Ksp or Solubility Product Constant is an equilibrium constant for the dissociation in an aqueous solution.
Molar solubility (S) is the concentration of the dissolved substance in a solution that is saturated.
Let the molar solubility be S upon dissociation.
PbBr₂ or Lead Bromide dissociates in pure water as follows:
PbBr₂ ----------> Pb⁺² + Br⁻
S 2S
Ksp = [Pb⁺²] [ Br⁻]
Ksp = (S) (2S)²
Ksp = 4S³
6.60 × 10⁻⁶ = 4S³
S = 0.0118M
Hence, the Molar solubility S is 0.0118M.
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Answer:
D
Explanation:
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The activation energy Ea can be related to rate constant (k) at temperature (T) through the equation:
ln(k2/k1) = Ea/R[1/T1 - 1/T2]
where :
k1 is the rate constant at temperature T1
k2 is the rate constant at temperature T2
R = gas constant = 8.314 J/K-mol
Given data:
k1 = 0.543 s-1; T1 = 25 C = 25+273 = 298 K
k2 = 6.47 s-1; T = 47 C = 47+273 = 320 K
ln(6.47/0.543) = Ea/8.314 [1/298 - 1/320]
2.478 = 2.774 *10^-5 Ea
Ea = 0.8934*10^5 J = 89.3 kJ
A binary compound of oxygen with another element is called oxide. An oxide is a binary compound of oxygen and another element. Oxygen combines with metals and non-metals to form respective oxides.