The isotopes of an element differ in the number or neutrons whereas the number of protons or electrons of a neutral atom stays the same. The molar mass of the element is based on the percent abundances of different isotopes and the individual molar mass of each isotope.
<u>Answer:</u> The fugacity coefficient of a gaseous species is 1.25
<u>Explanation:</u>
Fugacity coefficient is defined as the ratio of fugacity and the partial pressure of the gas. It is expressed as 
Mathematically,

Partial pressure of the gas is expressed as:

Putting this expression is above equation, we get:

where,
= fugacity coefficient of the gas
= fugacity of the gas = 25 psia
= mole fraction of the gas = 0.4
P = total pressure = 50 psia
Putting values in above equation, we get:

Hence, the fugacity coefficient of a gaseous species is 1.25
Answer:
4.42x10⁻¹⁹ J/molecule
Explanation:
At a double bond, there's sigma and a pi bond, and at a single bond, there's only a sigma bond. Thus, if the energy to break both sigma and pi is 614 kJ/mol, and the energy to break only the sigma bond is 348 kJ/mol, the energy to break only the pi bond is:
E = 614 - 348 = 266 kJ/mol
Knowing that 1 kJ = 1000 J, E = 266,000 J/mol
By Avogadro's number, 1 mol = 6.02x10²³ molecules, thus:
E = 266,000 J/mol * 1mol/6.02x10²³ molecules
E = 4.42x10⁻¹⁹ J/molecule