The electronic configuration of ‘N’ atom is 2, 5 and to have Octet in the valence shell it requires three more electrons.When two nitrogen atoms approach each other, each atom contributes 3 electrons for bonding.There are six electrons shared between two nitrogen atoms in the form of three pairs.Therefore, there is a triple bond between two nitrogen atoms in $N _{ 2 }$ molecules.
<h2>a)
The rate at which
is formed is 0.066 M/s</h2><h2>b)
The rate at which molecular oxygen
is reacting is 0.033 M/s</h2>
Explanation:
Rate law says that rate of a reaction is directly proportional to the concentration of the reactants each raised to a stoichiometric coefficient determined experimentally called as order.

The rate in terms of reactants is given as negative as the concentration of reactants is decreasing with time whereas the rate in terms of products is given as positive as the concentration of products is increasing with time.
Rate in terms of disappearance of
=
= 0.066 M/s
Rate in terms of disappearance of
= ![-\frac{1d[O_2]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7B1d%5BO_2%5D%7D%7Bdt%7D)
Rate in terms of appearance of
= ![\frac{1d[NO_2]}{2dt}](https://tex.z-dn.net/?f=%5Cfrac%7B1d%5BNO_2%5D%7D%7B2dt%7D)
1. The rate of formation of 
![-\frac{d[NO_2]}{2dt}=\frac{1d[NO]}{2dt}](https://tex.z-dn.net/?f=-%5Cfrac%7Bd%5BNO_2%5D%7D%7B2dt%7D%3D%5Cfrac%7B1d%5BNO%5D%7D%7B2dt%7D)
![\frac{1d[NO_2]}{dt}=\frac{2}{2}\times 0.066M/s=0.066M/s](https://tex.z-dn.net/?f=%5Cfrac%7B1d%5BNO_2%5D%7D%7Bdt%7D%3D%5Cfrac%7B2%7D%7B2%7D%5Ctimes%200.066M%2Fs%3D0.066M%2Fs)
2. The rate of disappearance of 
![-\frac{1d[O_2]}{dt}=\frac{d[NO]}{2dt}](https://tex.z-dn.net/?f=-%5Cfrac%7B1d%5BO_2%5D%7D%7Bdt%7D%3D%5Cfrac%7Bd%5BNO%5D%7D%7B2dt%7D)
![-\frac{1d[O_2]}{dt}=\frac{1}{2}\times 0.066M/s=0.033M/s](https://tex.z-dn.net/?f=-%5Cfrac%7B1d%5BO_2%5D%7D%7Bdt%7D%3D%5Cfrac%7B1%7D%7B2%7D%5Ctimes%200.066M%2Fs%3D0.033M%2Fs)
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Mass of KCl= 1.08 g
<h3>Further explanation</h3>
Given
1 g of K₂CO₃
Required
Mass of KCl
Solution
Reaction
K₂CO₃ +2HCl ⇒ 2KCl +H₂O + CO₂
mol of K₂CO₃(MW=138 g/mol) :
= 1 g : 138 g/mol
= 0.00725
From the equation, mol ratio K₂CO₃ : KCl = 1 : 2, so mol KCl :
= 2/1 x mol K₂CO₃
= 2/1 x 0.00725
= 0.0145
Mass of KCl(MW=74.5 g/mol) :
= mol x MW
= 0.0145 x 74.5
= 1.08 g