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AVprozaik [17]
3 years ago
14

Is the interaction between an ammonia ligand and a metal cation a lewis acid-base interaction?

Chemistry
1 answer:
snow_lady [41]3 years ago
3 0

Answer: Yes interaction between an ammonia ligand and a metal cation is a lewis acid-base interaction

Explanation:

According to the Lewis concept, an acid is defined as a substance that accepts electron pairs and base is defined as a substance which donates electron pairs.

As metal cation is short of electrons to complete its octet, thus it can easily accept an electron pair from ammonia which can easily donate its lone pair of electron and thus acts as lewis base.

M^{n+}+NH_3\rightarrow M(NH_3)_n

Thus interaction between an ammonia ligand and a metal cation is a lewis acid-base interaction

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A solution contains [Ba2+] = 5.0 × 10−5 M, [Zn2+] = 2.0 × 10−7 M, and [Ag+] = 3.0 × 10−5 M. Sodium oxalate (Na2C2O4) is slowly a
Jet001 [13]

Answer:

BaC₂O₄, then ZnC₂O₄, then Ag₂C₂O₄  

Explanation:

1. Calculate the equilibrium concentrations of oxalate ion

Let [C₂O₄²⁻] = c

(a) Barium oxalate

                 BaC₂O₄ ⇌   Ba²⁺   + C₂O₄²⁻

E/mol·L⁻¹:                   5.0 × 10⁻⁵     c

Ksp = [Ba²⁺][C₂O₄²⁻] = 5.0 × 10⁻⁵c = 1.5 × 10⁻⁸

c = (1.5 × 10⁻⁸)/(5.0 × 10⁻⁵) = 3.0 × 10⁻⁴ mol·L⁻¹

(b) Zinc oxalate

                ZnC₂O₄ ⇌   Zn²⁺   + C₂O₄²⁻

E/mol·L⁻¹:                 2.0 × 10⁻⁷      c

Ksp = [Zn²⁺][C₂O₄²⁻] = 2.0 × 10⁻⁷c = 1.35 × 10⁻⁹

c = (1.35 × 10⁻⁹)/(2.0 × 10⁻⁷) = 6.8 × 10⁻³ mol·L⁻¹

(c) Silver oxalate

                 Ag₂C₂O₄ ⇌   2Ag⁺   +   C₂O₄²⁻  

E/mol·L⁻¹:                      3.0 × 10⁻⁵       c

Ksp = [Ag⁺]²[C₂O₄²⁻] = (3.0× 10⁻⁵)²c = 9.0 × 10⁻¹⁰c = 1.1 × 10⁻¹¹

c = (1.1 × 10⁻¹¹)/(9.0 × 10⁻¹⁰) = 0.012 mol·L⁻¹

2. Decide the order of precipitation

BaC₂O₄ will precipitate when   c > 3.0 × 10⁻⁴ mol·L⁻¹

ZnC₂O₄ will precipitate when   c > 6.8 × 10⁻³ mol·L⁻¹

Ag₂C₂O₄ will precipitate when c > 0.028       mol·L⁻¹

This happens to be the order of increasing concentration of oxalate ion.

The order of precipitation is

BaC₂O₄, then ZnC₂O₄, then Ag₂C₂O₄

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