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Korolek [52]
3 years ago
7

A solution contains [Ba2+] = 5.0 × 10−5 M, [Zn2+] = 2.0 × 10−7 M, and [Ag+] = 3.0 × 10−5 M. Sodium oxalate (Na2C2O4) is slowly a

dded so that the following salts are formed. Salt BaC2O4. ZnC2O4. Ag2C2O4.
Ksp. 1.5 × 10−8. 1.35 × 10−9. 1.1 × 10−11
What is the order of the cations that would precipitate with the addition of C2O42−?

Every time I do this I keep getting the opposite of the answer. Can you please show your process so I can see where I am going wrong? Thank you!
Chemistry
1 answer:
Jet001 [13]3 years ago
4 0

Answer:

BaC₂O₄, then ZnC₂O₄, then Ag₂C₂O₄  

Explanation:

1. Calculate the equilibrium concentrations of oxalate ion

Let [C₂O₄²⁻] = c

(a) Barium oxalate

                 BaC₂O₄ ⇌   Ba²⁺   + C₂O₄²⁻

E/mol·L⁻¹:                   5.0 × 10⁻⁵     c

Ksp = [Ba²⁺][C₂O₄²⁻] = 5.0 × 10⁻⁵c = 1.5 × 10⁻⁸

c = (1.5 × 10⁻⁸)/(5.0 × 10⁻⁵) = 3.0 × 10⁻⁴ mol·L⁻¹

(b) Zinc oxalate

                ZnC₂O₄ ⇌   Zn²⁺   + C₂O₄²⁻

E/mol·L⁻¹:                 2.0 × 10⁻⁷      c

Ksp = [Zn²⁺][C₂O₄²⁻] = 2.0 × 10⁻⁷c = 1.35 × 10⁻⁹

c = (1.35 × 10⁻⁹)/(2.0 × 10⁻⁷) = 6.8 × 10⁻³ mol·L⁻¹

(c) Silver oxalate

                 Ag₂C₂O₄ ⇌   2Ag⁺   +   C₂O₄²⁻  

E/mol·L⁻¹:                      3.0 × 10⁻⁵       c

Ksp = [Ag⁺]²[C₂O₄²⁻] = (3.0× 10⁻⁵)²c = 9.0 × 10⁻¹⁰c = 1.1 × 10⁻¹¹

c = (1.1 × 10⁻¹¹)/(9.0 × 10⁻¹⁰) = 0.012 mol·L⁻¹

2. Decide the order of precipitation

BaC₂O₄ will precipitate when   c > 3.0 × 10⁻⁴ mol·L⁻¹

ZnC₂O₄ will precipitate when   c > 6.8 × 10⁻³ mol·L⁻¹

Ag₂C₂O₄ will precipitate when c > 0.028       mol·L⁻¹

This happens to be the order of increasing concentration of oxalate ion.

The order of precipitation is

BaC₂O₄, then ZnC₂O₄, then Ag₂C₂O₄

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umka2103 [35]

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4 0
3 years ago
calculate how many milliliters of 0.142 M NaOH are needed to completely neutralize 21.4 mL of 0.294 M H2C4H4O6.
Flura [38]

Answer:

The answer to your question is 88.7 ml

Explanation:

Data

Volume = ?

Concentration of NaOH = 0.142 M

Volume of H₂C₄H₄O₆ = 21.4 ml

Concentration of H₂C₄H₄O₆ = 0.294 M

Balanced chemical reaction

               2 NaOH + H₂C₄H₄O₆  ⇒  Na₂C₄H₄O₆  +  2H₂O

1.- Calculate the moles of H₂C₄H₄O₆

Molarity = moles/volume

Solve for moles

moles = Molarity x volume

Substitution

moles = 0.294 x 21.4/1000

Result

moles = 0.0063

2.- Use proportions to calculate the moles of NaOH

              2 moles of NaOH ------------------ 1 moles of H₂C₄H₄O₆

               x                           ------------------ 0.0063 moles

               x = (0.0063 x 2) / 1

               x = 0.0126 moles of NaOH

3.- Calculate the volume  of NaOH

Molarity = moles / volume

Solve for volume

Volume = moles/Molarity

Substitution

Volume = 0.0126/0.142

Result

Volume = 0.088 L or 88.7 ml

3 0
3 years ago
A 50.0-mL volume of 0.15 M HBr is titrated with 0.25 M KOH. Calculate the pH after the addition of 13.0 mL of KOH. Express your
Mazyrski [523]

Answer:

pH= 1.17

Explanation:

The neutralization reaction between HBr (acid) and KOH (base) is given by the following equation:

HBr(aq) + KOH(aq) → KBr(aq) + H₂O(l)

According to this equation, 1 mol of HBr reacts with 1 mol of KOH. Then, the moles can be expressed as the product between the molarity of the acid/base solution (M) and the volume in liters (V). So, we calculate the moles of acid and base:

<u>Acid</u>:

M(HBr) = 0.15 M = 0.15 mol/L

V(HBr) = 50.0 mL x 1 L/1000 mL = 0.05 L

moles of HBr = M(HBr) x V(HBr) = 0.15 mol/L x 0.05 L = 7.5 x 10⁻³ moles HBr

<u>Base</u>:

M(KOH) = 0.25 M = 0.25 mol/L

V(HBr) = 13.0 mL x 1 L/1000 mL = 0.013 L

moles of HBr = M(HBr) x V(HBr) = 0.25 mol/L x 0.013 L = 3.25 x 10⁻³ moles KOH

Now, we have: 7.5 x 10⁻³ moles HBr > 3.25 x 10⁻³ moles KOH

HBr is a strong acid and KOH is a strong base, so they are completely dissociated in water: the acid produces H⁺ ions and the base produces OH⁻ ions. So, the difference between the moles of HBr and the moles of KOH is equal to the moles of remaining H⁺ ions after neutralization:

moles of H⁺ = 7.5 x 10⁻³ moles HBr - 3.25 x 10⁻³ moles KOH = 4.25 x 10⁻³ moles H⁺

From the definition of pH:

pH = -log [H⁺]

The concentration of H⁺ ions is calculated from the moles of H⁺ divided into the total volume:

total volume = V(HBr) + V(KOH) = 0.05 L + 0.013 L = 0.063 L

[H⁺] = (moles of H⁺)/(total volume) = 4.25 x 10⁻³ moles/0.063 L = 0.067 M

Finally, we calculate the pH after neutralization:

pH = -log [H⁺] = -log (0.067) = 1.17

3 0
3 years ago
Which is formed by positive ions from a base and negative ions from an acid? a. Salt b. Vinegar
max2010maxim [7]

The formation of salt takes place by the sharing of positive ions from a base and negative ions from an acid.

This is based on the concept and principles of neutralization. The process of neutralization is the name of a chemical reaction between an acid and a base.

Hence, the correct option is a.

pH refers to a measure of how acidic or basic a solution is.

A pH is a measure of how basic or acidic a substance is. pH has a range of 0-14. A pH greater than 7 means the substance is basic.

A pH less than 7 means the substance is acidic. When the pH is exactly 7 that indicates that the substance is neutral.

Hence, the correct optiion is a.

The pH of a solution that has the same number of hydrogen ions as hydroxide ions is 7.

Hence, the correct option is c.

Baking soda has the greatest number of hydroxide ions.

Thus is because of the pH is 9. So, it will be more basic.

Hence, the correct option is a.

Hydrochloric acid will be least likely to completely dissolve in water.

Hence, the correct option is a.

Antacid is taken to get relieve from heartburn describes that the antacid is acidic and will raise the pH of the esophagus.

Hence, the correct option is c.

Acids measure below 7 describes the pH scale.

Hence, the correct option is a.

The order of these solutions from strong acid to strong base is  

Ammonia>battery acid>stomach acid>antacid>baking soda.

To know more about pH here

brainly.com/question/3775914

#SPJ4

3 0
9 months ago
Earth is unique because it is the _____.
astraxan [27]

Answer:

B. The only planet to support life.

Explanation:

5 0
3 years ago
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