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fenix001 [56]
3 years ago
15

Can some atoms exceed the limits of the octet rule in bonding? If so, give an example.

Chemistry
1 answer:
harkovskaia [24]3 years ago
6 0

Answer:

Yes. Example: <u>Sulfur hexafluoride (SF₆) molecule</u>

Explanation:

According to the octet rule, elements tend to form chemical bonds in order to have <u>8 electrons in their valence shell</u> and gain the stable s²p⁶ electronic configuration.

However, this rule is generally followed by main group elements only.

Exception: <u>SF₆ molecule</u>

In this molecule, six fluorine atoms are attached to the central sulfur atom by single covalent bonds.

<u>Each fluorine atom has 8 electrons in their valence shells</u>. Thus, it <u>follows the octet rule.</u>

Whereas, there are <u>12 electrons around the central sulfur atom</u> in the SF₆ molecule. Therefore, <u>sulfur does not follow the octet rule.</u>

<u>Therefore, the SF₆ molecule is known as a </u><u>hypervalent molecule</u><u> or expanded-valence molecule.</u>

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Given the following reaction: NH4SH (s) &lt;--&gt; NH3 (g) + H2S (g) If we start
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D. 0.3 M

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                                              NH4SH (s)      <-->            NH3 (g) + H2S (g)

Initial concentration              0.085mol/0.25L             0                 0

Change in concentration     -0.2M                               +0.2 M        +0.2M

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