Answer:
K(48.5°C) = 1.017 E-8 s-1
Explanation:
- CH3Cl + H2O → CH3OH + HCl
at T1 = 25°C (298 K) ⇒ K1 = 3.32 E-10 s-1
at T2 = 48.5°C (321.5 K) ⇒ K2 = ?
Arrhenius eq:
- K(T) = A e∧(-Ea/RT)
- Ln K = Ln(A) - [(Ea/R)(1/T)]
∴ A: frecuency factor
∴ R = 8.314 E-3 KJ/K.mol
⇒ Ln K1 = Ln(A) - [Ea/R)*(1/T1)]..........(1)
⇒ Ln K2 = Ln(A) - [(Ea/R)*(1/T2)].............(2)
(1)/(2):
⇒ Ln (K1/K2) = (Ea/R)* (1/T2-1/T1)
⇒ Ln (K1/K2) = (116 KJ/mol/8.3134 E-3 KJ/K.mol)*(1/321.5 K - 1/298 K)
⇒ Ln (K1/K2) = (13952.37 K)*(- 2.453 E-4 K-1)
⇒ Ln (K1/K2) = - 3.422
⇒ K1/K2 = e∧(-3.422)
⇒ (3.32 E-10 s-1)/K2 = 0.0326
⇒ K2 = (3.32 E-10 s-1)/0.0326
⇒ K2 = 1.017 E-8 s-1
Answer:
The standard enthalpy change for the reaction at 
is -2043.999kJ
Explanation:
Standard enthalpy change (
) for the given reaction is expressed as:
![\Delta H_{rxn}^{0}=[3mol\times \Delta H_{f}^{0}(CO_{2})_{g}]+[4mol\times \Delta H_{f}^{0}(H_{2}O)_{g}]-[1mol\times \Delta H_{f}^{0}(C_{3}H_{8})_{g}]-[5mol\times \Delta H_{f}^{0}(O_{2})_{g}]](https://tex.z-dn.net/?f=%5CDelta%20H_%7Brxn%7D%5E%7B0%7D%3D%5B3mol%5Ctimes%20%5CDelta%20H_%7Bf%7D%5E%7B0%7D%28CO_%7B2%7D%29_%7Bg%7D%5D%2B%5B4mol%5Ctimes%20%5CDelta%20H_%7Bf%7D%5E%7B0%7D%28H_%7B2%7DO%29_%7Bg%7D%5D-%5B1mol%5Ctimes%20%5CDelta%20H_%7Bf%7D%5E%7B0%7D%28C_%7B3%7DH_%7B8%7D%29_%7Bg%7D%5D-%5B5mol%5Ctimes%20%5CDelta%20H_%7Bf%7D%5E%7B0%7D%28O_%7B2%7D%29_%7Bg%7D%5D)
Where 
refers standard enthalpy of formation
Plug in all the given values from literature in the above equation:
![\Delta H_{rxn}^{0}=[3mol\times (-393.509kJ/mol)]+[4mol\times (-241.818kJ/mol)]-[1mol\times (-103.8kJ/mol)]-[5mol\times (0kJ/mol)]=-2043.999kJ](https://tex.z-dn.net/?f=%5CDelta%20H_%7Brxn%7D%5E%7B0%7D%3D%5B3mol%5Ctimes%20%28-393.509kJ%2Fmol%29%5D%2B%5B4mol%5Ctimes%20%28-241.818kJ%2Fmol%29%5D-%5B1mol%5Ctimes%20%28-103.8kJ%2Fmol%29%5D-%5B5mol%5Ctimes%20%280kJ%2Fmol%29%5D%3D-2043.999kJ)
Answer:
Four
Step-by-step explanation:
The <em>superscripts</em> in an electron configuration tell us how many electrons are in a subshell.
If the electron configuration is 1s¹ 2s¹2p², the total number of electrons is
1 + 1 + 2 = 4
The atom contains four electrons.
<em>Note</em>: this atom is in an <em>excited state</em>, because the 1s and 2s subshells can each hold one more electron.
