From ideal gas equation that is PV=nRT
n(number of moles)=PV/RT
P=760 torr
V=4.50L
R(gas constant =62.363667torr/l/mol
T=273 +273=298k
n is therefore (760torr x4.50L) /62.36367 torr/L/mol x298k =0.184moles
the molar mass of NO2 is 46 therefore density= 0.184 x 46=8.464g/l
The mass of ammonium chloride that must be added is : ( A ) 4.7 g
<u>Given data :</u>
Volume of water ( V ) = 250 mL = 0.25 L
pH of solution = 4.85
Kb = 1.8 * 10⁻⁵
Kw = 10⁻¹⁴
Given that the dissolution of NH₄Cl gives NH₄⁺⁺ and Cl⁻ ions the equation is written as :
NH₄CI + H₂O ⇄ NH₃ + H₃O⁺
where conc of H₃O⁺
[ H₃O⁺ ] =
and Ka = Kw / Kb
∴ Ka = 5.56 * 10⁻¹⁰
Next step : Determine the concentration of H₃O⁺ in the solution
pH = - log [ H₃O⁺ ] = 4.85
∴ [ H₃O⁺ ] in the solution = 1.14125 * 10⁻⁵
Next step : Determine the concentration of NH₄CI in the solution
C = [ H₃O⁺ ]² / Ka
= ( 1.14125 * 10⁻⁵ )² / 5.56 * 10⁻¹⁰
= 0.359 mol / L
Determine the number of moles of NH₄CI in the solution
n = C . V
= 0.359 mol / L * 0.25 L = 0.08979 mole
Final step : determine the mass of ammonium chloride that must be added to 250 mL
mass = n * molar mass
= 0.08979 * 53.5 g/mol
= 4.80 g ≈ 4.7 grams
Therefore we can conclude that the mass of ammonium chloride that must be added is 4.7 g
Learn more about ammonium chloride : brainly.com/question/13050932
Answer:
2.772 seconds
Explanation:
Given that;
t1/2 = 0.693/k
Where;
t1/2 = half life of the reaction
k= rate constant
Note that decomposition is a first order reaction since the rate of reaction depends on the concentration of one reactant
t1/2 = 0.693/2.5 x 10-1 s-1
t1/2= 2.772 seconds
Answer:
The answer is 0.0698 M
Explanation:
The concentration was prepared by a serial dilution method.
The formula for the preparation I M1V1 = M2V2
M1= the concentration of the stock solution = 0.171 M
V1= volume of the stock solution taken = 200 mL
M2 = the concentration produced
V2 = the volume of the solution produced = 940 mL
Substitute these values in the formula
0.171 × 200 = 490 × M2
34.2 = 490 × M2
Make M2 the subject of the formula
M2 = 34.2/490
M2 = 0.069795
M2 = 0.0698 M ( 3 s.f)
The concentration of the Chemist's working solution to 3 significant figures is 0.0698M