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The glass capillary having one end closed and one open end is generally used for the determination of melting point of the sample. From the open end, the sample is put into the capillary, the sample must be firmly packed as the melting point is an intrinsic property that means it is independent of sample size. So, in order to determine the melting point of the sample small sample in the capillary is sufficient to measure the melting point of the sample. To obtain the more consistent value of melting point one must pack the sample firmly in the capillary.
Hence, when determining the melting point of a substance, one should use a small sample in the capillary and the sample should be firmly packed.
Answer:
a) 0.525 mol
b) 0.525 mol
c) 0.236 mol
Explanation:
The combustion reactions (partial and total) will be:
C₇H₁₆ + (15/2)O₂ → 7CO + 8H₂O
C₇H₁₆ + 11O₂ → 7CO₂ + 8H₂O
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2C₇H₁₆ + (37/2)O₂ → 7CO + 7CO₂ + 16H₂O
It means that the reaction will form 50% of each gas.
a) 0.525 mol of CO
b) 0.525 mol of CO₂
c) The molar mass of heptane is: 7*12 g/mol of C + 16*1 g/mol of H = 100 g/mol
So, the number of moles is the mass divided by the molar mass:
n = 11.5/100 = 0.115 mol
For the stoichiometry:
2 mol of C₇H₁₆ -------------- (37/2) mol of O₂
0.115 mol of C₇H₁₆ --------- x
By a simple direct three rule:
2x = 2.1275
x = 1.064 mol of O₂
Which is the moles of oxygen that reacts, so are leftover:
1.3 - 1.064 = 0.236 mol of O₂
