HELP ASAP! Chemical reactions involving liquids only will be influenced by ALL of the following EXCEPT: a) temperature of the sy
1 answer:
<span>Chemical reactions involving only liquids will be influenced by ALL of the following EXCEPT: </span><span><span>c) size of reactant particles d) pressure of the system.
</span>Reason:
1) As per Arrhenius theory, rate of chemical reactions is influence by temperature. Mathematically it is expressed as: k = A exp(-Ea/RT)
</span>where, k = rate constant, A = collision frequency, Ea = activation energy, T = temp. From above relation, it can be seen that, chemical reactions involving only liquids will be influenced temperature.
2) Also, if know that, rates of chemical reactions is mathematically expressed as:![Rate = [A]^{x} B^{y}....](https://tex.z-dn.net/?f=%20Rate%20%3D%20%5BA%5D%5E%7Bx%7D%20B%5E%7By%7D....%20%20)
,
where A, B, .. are the reactants.
From above relation, it can be seen that, chemical reactions involving only liquids will be influenced concentration i.e. number of particle.
3) However, since all the reactant and catalyst used (if any) is in liquid state, particle size of same will not influence the reaction.
4) Also, since there are no gas-phase reactant, pressure will not affect the reaction.
</span>Reason:
1) As per Arrhenius theory, rate of chemical reactions is influence by temperature. Mathematically it is expressed as: k = A exp(-Ea/RT)
</span>where, k = rate constant, A = collision frequency, Ea = activation energy, T = temp. From above relation, it can be seen that, chemical reactions involving only liquids will be influenced temperature.
2) Also, if know that, rates of chemical reactions is mathematically expressed as:
where A, B, .. are the reactants.
From above relation, it can be seen that, chemical reactions involving only liquids will be influenced concentration i.e. number of particle.
3) However, since all the reactant and catalyst used (if any) is in liquid state, particle size of same will not influence the reaction.
4) Also, since there are no gas-phase reactant, pressure will not affect the reaction.
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Answer : The values of are
respectively.
Explanation :
The given balanced chemical reaction is,
First we have to calculate the enthalpy of reaction .
where,
= enthalpy of reaction = ?
n = number of moles
= standard enthalpy of formation of gaseous benzene = 82.93 kJ/mol
= standard enthalpy of formation of liquid benzene = 49.04 kJ/mol
Now put all the given values in this expression, we get:
Now we have to calculate the entropy of reaction .
where,
= entropy of reaction = ?
n = number of moles
= standard entropy of formation of gaseous benzene = 269.2 J/K.mol
= standard entropy of formation of liquid benzene = 173.26 J/K.mol
Now put all the given values in this expression, we get:
Now we have to calculate the Gibbs free energy of reaction .
As we know that,
At room temperature, the temperature is .
Therefore, the values of are
respectively.