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2 years ago

The reaction system

Chemistry

1 answer:

tankabanditka [31]2 years ago

3 0

Answer:

e. As equilibrium is reestablished, the partial pressure of hydrogen decreases.

Explanation:

Hello,

In this case, for the given chemical reaction:

$CS_2(g) + 4H_2(g)\rightleftharpoons CH_4(g) + 2H_2S(g)$

Considering the Le Chatelier's principle which states that adding more reactant shifts the reaction towards the products, condition that is related with the doubling of the hydrogen partial pressure, we can notice that e. As equilibrium is reestablished, the partial pressure of hydrogen decreases since the addition of hydrogen will be used to form more methane and hydrogen sulfide, for that reason, its amount is decreased to reattain equilibrium.

Regards.

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2 years ago

Mixtures of benzene and cyclohexane exhibit ideal behavior. A solution was created containing 1.5 moles of liquid benzene and 2.

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Answer:

Vapour pressure of cyclohexane at 50°C is 490torr

Vapour pressure of benzene at 50°C is 90torr

Explanation:

Using Raoult's law, pressure of a solution is defined by the sum of the product sbetween mole fraction of both solvents and pressure of pure solvents.

$P_{solution} = X_{A}P^0_{A}+X_{B}P^0_{B}$

In the first solution:

$X_{cyclohexane}=\frac{2.5mol}{2.5mol+1.5mol} =0.625$

$X_{benzene}=\frac{1.5mol}{2.5mol+1.5mol} =0.375$

$340torr = 0.625P^0_{A}+0.375P^0_{B}$ (1)

For the second equation:

$X_{cyclohexane}=\frac{3.5mol}{3.5mol+1.5mol} =0.700$

$X_{benzene}=\frac{1.5mol}{3.5mol+1.5mol} =0.300$

$370torr = 0.700P^0_{A}+0.300P^0_{B}$ (2)

Replacing (2) in (1):

$340torr = 0.625P^0_{A}+0.375(1233.3-2.333P^0_{A})$

$340torr = 0.625P^0_{A}+462.5-0.875P^0_{A}$

-122.5torr = -0.250P°A

$P^0_{A} = 490 torr$

Vapour pressure of cyclohexane at 50°C is 490torr

And for benzene:

$370torr = 0.700*490torr+0.300P^0_{B}$

$P^0_{B}=90torr$

Vapour pressure of benzene at 50°C is 90torr

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If more heat is removed from the reaction the rate of reaction change as below to counter the action

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explanation

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The position of equilibrium moves to the right since removing heat led to decrease of temperature and more zinc chloride is produced.

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3 years ago

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