Which correctly describes elements in the same group? select one:

A titration of 25.0 mL of a solution of the weak base aniline, C6H5NH2, requires 25.67 mL of 0.175 M HCl to reach the equivalenc

Lorico [155]

Answer:

a. 0.180M of C₆H₅NH₂

b. 0.0887M C₆H₅NH₃⁺

c. pH = 2.83

Explanation:

a. Based in the chemical equation:

C₆H₅NH₂(aq) + HCl(aq) → C₆H₅NH₃⁺(aq) + Cl⁻(aq)

<em>1 mole of aniline reacts per mole of HCl</em>

Moles required to reach equivalence point are:

Moles HCl = 0.02567L ₓ (0.175mol / L) = 4.492x10⁻³ moles HCl = moles C₆H₅NH₂

As the original solution had a volume of 25.0mL = 0.0250L:

4.492x10⁻³ moles C₆H₅NH₂ / 0.0250L = 0.180M of C₆H₅NH₂

b. At equivalence point, moles of C₆H₅NH₃⁺ are equal to initial moles of C₆H₅NH₂, that is 4.492x10⁻³ moles

But now, volume is 25.0mL + 25.67mL = 50.67mL = 0.05067L. Thus, molar concentration of C₆H₅NH₃⁺ is:

[C₆H₅NH₃⁺] = 4.492x10⁻³ moles / 0.05067L = 0.0887M C₆H₅NH₃⁺

c. At equivalence point you have just 0.0887M C₆H₅NH₃⁺ in solution. C₆H₅NH₃⁺ has as equilibrium in water:

C₆H₅NH₃⁺(aq) + H₂O(l) → C₆H₅NH₂ + H₃O⁺

Where Ka = Kw / Kb = 1x10⁻¹⁴ / 4.0x10⁻¹⁰ =

When the system reaches equilibrium, molar concentrations are:

[C₆H₅NH₃⁺] = 0.0887M - X

[C₆H₅NH₂] = X

[H₃O⁺] = X

Replacing in Ka formula:

2.5x10⁻⁵ = [X] [X] / [0.0887M - X]

2.2175x10⁻⁶ - 2.5x10⁻⁵X = X²

0 = X² + 2.5x10⁻⁵X - 2.2175x10⁻⁶

Solving for X:

X = -0.0015 → False solution. There is no negative concentrations.

X = 0.001477 → Right solution.

As [H₃O⁺] = X, [H₃O⁺] = 0.001477

Knowing pH = -log [H₃O⁺]

pH = -log 0.001477

7 0

2 years ago

16. Explain why antifreeze is used in vehicle radiators. Use your knowledge of the properties of

Fynjy0 [20]

Answer:

Antifreeze is whats used to keep your engine cool without freezing.

Explanation:

it keeps the engine from overheating.

It also prevents corrosion.

Here is a quote from google "Antifreeze works because the freezing and boiling points of liquids are “colligative” properties. This means they depend on the concentrations of “solutes,” or dissolved substances, in the solution. A pure solution freezes because the lower temperatures cause the molecules to slow down"

That quote is from "The Science Behind Antifreeze"

If you have any questions feel free to ask in the comments.

4 0

3 years ago

Suppose the half-life is 9.0 s for a first order reaction and the reactant concentration is 0.0741 M 50.7 s after the reaction s

bazaltina [42]

<u>Answer:</u> The time taken by the reaction is 84.5 seconds

<u>Explanation:</u>

The equation used to calculate half life for first order kinetics:

$k=\frac{0.693}{t_{1/2}}$

where,

$t_{1/2}$ = half-life of the reaction = 9.0 s

k = rate constant = ?

Putting values in above equation, we get:

$k=\frac{0.693}{9}=0.077s^{-1}$

Rate law expression for first order kinetics is given by the equation:

$k=\frac{2.303}{t}\log\frac{[A_o]}{[A]}$ ......(1)

where,

k = rate constant = $0.077s^{-1}$

t = time taken for decay process = 50.7 sec

$[A_o]$ = initial amount of the reactant = ?

[A] = amount left after decay process = 0.0741 M

Putting values in equation 1, we get:

$0.077=\frac{2.303}{50.7}\log\frac{[A_o]}{0.0741}$

$[A_o]=3.67M$

Now, calculating the time taken by using equation 1:

$[A]=0.0055M$

$k=0.077s^{-1}$

$[A_o]=3.67M$

Putting values in equation 1, we get:

$0.077=\frac{2.303}{t}\log\frac{3.67}{0.0055}\\\\t=84.5s$

Hence, the time taken by the reaction is 84.5 seconds

6 0

3 years ago

The game of kickball begins with the ball being rolled toward a player. The player then kicks the ball across the field. What is

hammer [34]

Answer:

C. The Speed of the ball depends on the force used to kick it.

Explanation:

6 0

2 years ago

Read 2 more answers

HELP PLEASE!! (100 points)

MrRa [10]

Answer:

As you cool a matter to absolute zero, their kinetic energy reduces significantly and the molecules slows down and begins to aggregate together. ... As heat is added, the molecules gain more kinetic energy. This shown in their increase motion. When heat is withdrawn, the particles slows down hope this helped

3 0

2 years ago