Answer:
A. The total mass of the reactants in a reaction equals the total mass of the product(s).
Explanation:
The law of conversation of matter tells us that in a chemical reaction, matter is never created or destroyed, it's simply converted from one form to another. So the mass of reactants should always equal the mass of the products in a chemical reaction.
Answer: Physical property
Explanation: length and dimensions are under physical properties of matter.
Answer:
Four possible isomers (1–4) for the natural product essramycin. The structure of compound 1 was attributed to essramycin by 1H NMR, 13C NMR, HMBC, HRMS, and IR experiments.
Explanation:
Three synthetic routes were used to prepare all four compounds (Figure 2A). All three reactions utilize 2-(5-amino-4H-1,2,4-triazol-3-yl)-1-phenylethanone (5) as the precursor, whereas each uses different esters (6–8) to construct the pyrimidinone ring. Isomer 1 was prepared by reaction A, which used triazole 5 and ethyl acetoacetate (6) in acetic acid. This was the reaction used in syntheses of essramycin by the Cooper and Moody laboratories.3,4 Reaction B produced compound 2 (minor product) and compound 3 (major product), which were separated chromatographically. This reaction allowed reagent 5 to react with ethyl 3-ethoxy-2-butenoate (7) in the presence of sodium in methanol, under reflux for 24 h. Compound 4 was prepared by reaction C, which was obtained by reflux of 5 and methyl 2-butynoate (8) in n-butanol.
The first three quantum numbers for electrons located in subshell 4s are :
Answer:
See Explanation
Explanation:
Let us consider the first two reactions, the initial concentration of CO was held constant and the concentration of Hbn was doubled.
2.68 * 10^-3/1.34 * 10^-3 = 6.24 * 10^-4/3.12 * 10^-4
2^1 = 2^1
The rate of reaction is first order with respect to Hbn
Let us consider the third and fourth reactions. The concentration of Hbn is held constant and that of CO was tripled.
1.5 * 10^-3/5 * 10^-4 = 1.872 * 10^-3/6.24 * 10^-4
3^1 = 3^1
The reaction is also first order with respect to CO
b) The overall order of reaction is 1 + 1=2
c) The rate equation is;
Rate = k [CO] [Hbn]
d) 3.12 * 10^-4 = k [5 * 10^-4] [1.34 * 10^-3]
k = 3.12 * 10^-4 /[5 * 10^-4] [1.34 * 10^-3]
k = 3.12 * 10^-4/6.7 * 10^-7
k = 4.7 * 10^2 mmol-1 L s-1
e) The reaction occurs in one step because;
1) The rate law agrees with the experimental data.
2) The sum of the order of reaction of each specie in the rate law gives the overall order of reaction.
