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Natalija [7]
3 years ago
8

How is enthalpy used to predict whether a reaction is endothermic or exothermic? when the enthalpy of the reactants is higher th

an the enthalpy of the products, the reaction is endothermic. when the enthalpy of the products is higher than the enthalpy of the reactants, the reaction is exothermic. when the enthalpy change of the reaction is positive, the reaction is exothermic. when the enthalpy change of the reaction is positive, the reaction is endothermic.
Chemistry
2 answers:
mafiozo [28]3 years ago
8 0
When the enthalpy change of the reaction is positive the reaction is endothermic
this means that the reaction is absorbing energy from the surrounding to the vessel
AleksAgata [21]3 years ago
4 0

The correct option is this: WHEN THE ENTHALPY CHANGE OF THE REACTION IS POSITIVE, THE REACTION IS ENDOTHERMIC.

A chemical reaction can be an exothermic reaction or an endothermic reaction based on whether it absorb or give out energy when it is occurring. An exothermic reaction is a type of reaction that gives out energy when it is occurring. The enthalpy change of exothermic reactions is always negative. An endothermic reaction is a type of chemical reaction in which energy is absorbed from the environment. The enthalpy change of endothermic reaction is always positive.

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A 0.879 g sample of a CaCl2 ∙ 2 H2O / K2C2O4 ∙ H2O solid salt mixture is dissolved in 150 mL of deionized water. A precipitate f
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a. CaCl₂.2 H₂O (aq) + K₂C₂O₄. H₂O (aq) ----> 2 KCl + CaC₂O₄ (s) + 3 H₂0 (l)

b. Ca²+ (aq) + C₂O₄²- (aq) ----> CaC₂O₄ (s)

C. moles of CaCl₂.2 H₂O reacted in the mixture = 0.00222 moles

d. Mass of CaCl₂.2 H₂O reacted = 0.326 g

e. Moles of K₂C₂O₄.2 H₂O reacted = 0.00222 moles

f. Mass of K₂C₂O₄.H₂O reacted = 0.408 g

g. mass of K₂C₂O₄.H₂O remaining unreacted = 0.145 g

h. Percent by mass CaCl₂.2 H₂O = 37.1%

Percent by mass of K₂C₂O₄.H₂O = 62.9%

Explanation:

a. Molecular equation of the reaction is given below :

CaCl₂.2 H₂O (aq) + K₂C₂O₄. H₂O (aq) ----> 2 KCl + CaC₂O₄ (s) + 3 H₂0 (l)

b. The net ionic equation is given below

Ca²+ (aq) + C₂O₄²- (aq) ----> CaC₂O₄ (s)

C. mass CaC₂O₄ produced = 0.284 g, molar mass of CaC₂O₄ = 128 g/mol

moles CaC₂O₄ produced = 0.284 g / 128 g/mol = 0.00222 moles

Mole ratio of CaC₂O₄ and CaCl₂.2 H₂O is 1 : 1, therefore moles of CaCl₂.2 H₂O reacted in the mixture = 0.00222 moles

d. Mass of CaCl₂.2 H₂O reacted in the mixture = number of moles × molar mass

Molar mass of CaCl₂.2 H₂O = 147 g/mol

Mass of CaCl₂.2 H₂O reacted = 0.00222 moles × 147 g/mol = 0.326 g

e. Mole ratio of K₂C₂O₄.2 H₂O and CaC₂O₄ is 1 : 1, therefore, moles of K₂C₂O₄.2 H₂O reacted = 0.00222 moles

f. Mass of K₂C₂O₄.H₂O reacted in the mixture = number of moles × molar mass

Molar mass of K₂C₂O₄.H₂O = 184 g/mol

grams K2C2O4-H2O reacted = 0.00222 moles 184 g/mole = 0.408 g

g. Mass of sample = 0.879 g

mass of CaCl₂.2 H₂O in sample completely used up = 0.326 g

mass of K₂C₂O₄.H₂O in sample = 0.879 g - 0.326 g = 0.553 g

mass of K₂C₂O₄.H₂O remaining unreacted = 0.553 g - 0.408 g = 0.145 g

h. Percent by mass CaCl₂.2 H₂O = 0.326 /0.879 x 100% = 37.1%

Percent by mass of K₂C₂O₄.H₂O = 0.553/0.879 × 100% = 62.9%

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