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jarptica [38.1K]
3 years ago
11

Which flask has the solution with the lowest freezing point

Chemistry
1 answer:
scZoUnD [109]3 years ago
8 0

Answer:

Here's what I get  

Explanation:

Assume you have 0. 1 mol·kg⁻¹ solutions of A) KCl, B) CH₃OH, C) Ba(OH)₂, and D) CH₃COOH.

The formula for freezing point depression is

\Delta T_{f} = iK_{f}b

Where

  b = the molal concentration

K_f = the freezing point depression constant

    i = the van't Hoff i factor

The i-factor is the number of solute particles produced by one formula unit of the substance.

The only difference in the solutions is the i-factor of the solutes.

A) KCl

KCl(aq) ⟶ K⁺(aq) +Cl⁻(aq); i = 2

B) CH₃OH

Methanol is a nonelectrolyte.

CH₃OH(aq) ⟶ CH₃OH(aq); i = 1

C) Ba(OH)₂

Ba(OH)₂(aq) ⟶ Ba²⁺(aq) + 2OH⁻(aq); i = 3

D) CH₃COOH

CH₃COOH(aq) ⇌ CH₃COO⁻(aq)+ H⁺(aq); i ⪆ 1

The Ba(OH)₂ solution has the greatest i-value. It therefore has the greatest freezing point depression and the lowest freezing point.

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Rank the following salts in order of decreasing pH of their 0.1 M aqueous solutions.(a) FeCl2, FeCl3, MgCl2, KClO2 .(b) NH4Br, N
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Answer:

a) FeCl2, FeCl3, MgCl2, KClO2.

KClO2 --> K+ + ClO2-; ClO2- will hydrolyse to form HClO +OH-

Mg+2, Fe+2 and Fe+3 ions will form acidic solutions, since theyfom slightly amount of

Mg+2 + 2H2O <-> Mg(OH)2 + 2H+

Fe+2 + 2H2O <-> Fe(OH)2 + 2H+

Fe+3 + 3H2O <-> Fe(OH)3 + 3H+

Therefore;

decreasing pH is high pH to low pH:

KClO2 > MgCl2 > FeCl2 > FeCl3

b) NH4Br, NaBrO2, NaBr, NaClO2.

NH4Br is acidic, forms NH4+ and NH4+ dnates H+ to form NH3 andH+

NaBrO2 is basic, forms Na+ + BrO2- then H2O + BrO2- HBrO2

NABr is neutral, NaClO2 is basics, forms Na+ + ClO2-then H2O + ClO2- HClO2

decreasig pH:

NaClO2 > NaBrO2 > NaBr >NH4Br

Note that HClO2 is stronger acid than HBrO2, therefore, expectmore HBrO2 formation

NaBrO2 > NaClO2 > NaBr >NH4Br

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During a laboratory experiment, 36.12 grams of Aboz was formed when O2 reacted with aluminum metal at 280.0 K and 1.4 atm. What
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Answer:

8.70 liters

Explanation:

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First we <u>convert 36.12 g of AI₂O₃ into moles</u>, using its <em>molar mass</em>:

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Then we <u>convert AI₂O₃ moles into O₂ moles</u>, using the stoichiometric coefficients of the reaction:

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We can now use the <em>PV=nRT equation</em> to <u>calculate the volume</u>, V:

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