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Dmitrij [34]
3 years ago
11

200 grams of an organic sample which contains only carbon, hydrogen, and oxygen is analyzed and found to contain 97.30 grams of

carbon, 16.22 grams of hydrogen and the remainder oxygen. What is the empirical formula for the compound?

Chemistry
2 answers:
faltersainse [42]3 years ago
4 0

Answer:

The Empirical formula of an organic compound is=C_3H_6O_2

Explanation:

Mass of an organic compound = 200 g

Mass of carbon = 97.30 g

moles of carbon = \frac{97.30 g}{12 g/mol}=8.108 mol

Mass of hydrogen = 16.22 g

Moles of hydrogen = \frac{16.22 g}{1 g/mol}=16.220 mol

Mass of oxygen = 200 g - 97.30 g - 16.22 g = 86.48 g

Moles of oxygen =\frac{86.48 g}{16 g/mol}=5.405 mol

Divide the all the moles of element with smallest value of moles.

Carbon = \frac{8.108 mol}{5.405 mol}=1.5

Hydrogen = \frac{16.220 mol}{5.405 mol}=3

Oxygen =\frac{5.405 mol}{5.405 mol}=1

Empirical formula =C_{1.5}H_3O_1

Converting them into whole number ratios.

Empirical formula =C_3H_6O_2

ipn [44]3 years ago
3 0
The empirical formula for 200 grams of an organic sample which contains carbon,hydrogen, and oxygen is C3H6O

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Answer:

PCO2  = 0.6 25 atm

PSO2  = 1.2 75 atm

PO2 = 0.6  atm

Explanation:

Step 1: Data given

Volume = 10.0 L

Temperature = 100.0 °C

Pressure = 3.10 °C

After reaction, the temperature returns to 100.0 ∘C, and the mixture of product gases (CO2, SO2, and unreacted O2) is found to have a pressure of 2.50 atm

Step 2: The balanced equation

CS2(g)+3O2(g)→CO2(g)+2SO2(g)

Step 3: Name the reactants and products

a = CS2

b = O2 before reaction

c = CO2

d = SO2

e = nS O2 after reaction with n = the number of moles

Step 4: Calculate moles before reaction

PV = nRT

n = PV/(RT)

(na + nb) = (3.10atm) * (10.0L) / ((0.08206 Latm/moleK) * (373.15K))

(na + nb) = 1.0124

Step 5: Calculate moles after reaction

PV = nRT

n = PV/(RT)

nc + nd + ne) = PV/(RT) = (2.50 atm)*(10.0L) / ((0.08206 Latm/moleK)*(373.15K))

(nc + nd + ne) = 0.816 moles

Step 6: Calculate mol fraction

For  1 mole CS2 we need 3 moles O2  to produce 1 mole of CO2 and 2 moles of SO2

moles O2 remaining = ne = nb - 3na

moles CO2 produced = nc = na

moles SO2 producted = nd = 2na

(nc + nd + ne) = 0.816 moles = nb - 3na + na + 2na = 0.816

nb = 0.816

. (na + nb) = 1.0124

na = 1.0124 moles - 0.816 moles = 0.208

which leads to  

nc = na = 0.208

nd = 2na = 2*0.208 = 0.416

ne = 0.816 - 3*0.208 = 0.192

mole fraction CO2 = 0.208 / (0.208 + 0.416 + 0.192) = 0.25

mole fraction SO2 = 0.416 / (0.208 + 0.416 + 0.192) = 0.5 1

mole fraction O2 = 0.192 /(0.208 + 0.416 + 0.192) = 0.24

Step 6: Calculate partial pressure

PCO2 = 0.25 * 2.50 atm = 0.6 25 atm

PSO2 = 0.51 * 2.50 atm = 1.2 75 atm

PO2 = 0.24 * 2.50 atm = 0.6  atm

Step 7: Control results

now let's verify a couple of things

PV = nRT

P = nRT/V

before rxn

P = (0.208 + 0.816) * (0.08206 L*atm/mole*K) * (373.15K) / (10.0L) ≈ 3.10 atm

after rxn

P = ((0.208 +0.416+0.192) * (0.08206 L*atm/mole*K) * (373.15K) / (10.0L) ≈ 2.50 atm

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