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stepan [7]
3 years ago
11

he reported molar absorptivity of Red Dye #3 is 1.217 L mol-1 cm-1. If a solution of Red Dye #3 displays an absorbance of 0.699

in a cuvette that is 1.526 cm in length, what is the concentration of the dye in solution? Report your response to three digits after the decimal. _____ M
Chemistry
1 answer:
Svetach [21]3 years ago
3 0

Answer:

Concentration of the solution is 0.376M

Explanation:

Lambert-Beer's law describes the absorbance of a solution that is directely proportional to concentration of the solution, molar absorptivity and path length. The law is:

A = ε×C×l

<em>Where A is absorbance (0.699 for Red Dye #3), ε is molar absorptivity (1.217L mol⁻¹cm⁻¹), C is concentration of solution and l is path length (1.526cm)</em>

Replacing:

0.699 = 1.217L mol⁻¹cm⁻¹×C×1.526cm

C = 0.3764 mol/L

<em>Concentration of the solution is 0.376M</em>

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Consider the reaction of NO and CO to form N2 and CO2, according to the balanced equation: 2 NO (g) + 2 CO (g) → N2 (g) + 2 CO2
Gekata [30.6K]

The image is not given in the question, it is attached below:

<u>Answer:</u> The excess reactant is NO, the limiting reactant is CO and the products are shown in the image attached below.

<u>Explanation:</u>

In the given image:

Red spheres represent oxygen atoms, blue spheres represent nitrogen atoms and black spheres represent carbon atoms

The combination of 1 black and 2 red spheres will represent carbon dioxide (CO_2) compound

The combination of 2 blue spheres will represent nitrogen molecule (N_2)

The combination of 1 blue and 1 red sphere will represent nitrogen monoxide (NO) compound

The combination of 1 black and 1 red sphere will represent nitrogen monoxide (NO) compound

Limiting reagent is defined as the reagent which is completely consumed in the reaction and limits the formation of the product.

Excess reagent is defined as the reagent which is left behind after the completion of the reaction.

We are given:

Given moles of NO = 6 moles

Given moles of CO = 4 moles

For the given chemical equation:

2NO(g)+2CO(g)\rightarrow N_2(g)+2CO_2(g)

By stoichiometry of the reaction:

If 2 moles of CO reacts with 2 moles of NO

So, 4 moles of CO will react with = \frac{2}{2}\times 4=4mol of NO

As the given amount of NO is more than the required amount. Thus, it is present in excess and is considered as an excess reagent.

Thus, CO is considered a limiting reagent because it limits the formation of the product.

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3 years ago
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What is the concentration of a solution containing 1.11 g sugar (sucrose, C12H22O11, MW = 342.3 g/mol, d = 1.587 g/cm3) in 432 m
djyliett [7]

Answer:

0.0075 M

0.0060 m

Explanation:

Our strategy here is to use the definition of molarity and molality to solve this question.

The molarity is the number of moles of solute, sucrose in this case, per liter of solution.

The molality is the number of moles of solute per kilogram of solvent.

So the molarity of the  solution is

M = moles of solute/ V solution

As we see we need the volume of solution since we are only given the volume of solvent, but this will be easy to compute since we have the density of  sucrose.

So determine the moles of sucrose , and the volume of solution:

Moles sucrose = 1.11 g/342.3 g/mol = 3.24 x 10⁻³ M

Volume of solution = Vol Sucrose + Vol glycerine

d = m/V ⇒ Vsucrose = m / d = 1.11 g/ 1.587 g/cm³ = 0.70 cm³

Vol solution = 432 mL + 0.70 mL = 432.7 mL  (1cm³  = 1 mL)

Vol solution = 432.7 mL x 1 L / 1000 mL = 0.4327 L

⇒ M = 3.2 x 10⁻³  mol / 0.4327 L = 0.0075  M

For the molarity what we need is to first calculate the kilograms of glycerine from the given density:

d = m/v ⇒ m = d x v = 1.261 g/cm³ x  432 cm³ = 544.75 g

Converting to Kg:

544.75 g x 1 Kg/ 1000 g = 0.544 kg

Now the molality is

m = mol sucrose/ kg solvent = 3.24 x 10⁻³ mol / 0.544 Kg = 0.0060 m

Note: In the calculation for  volume of solution we could have approximated it to that of just glycerine, but since the density of sucrose was given we calculated the total volume of solution to be more rigorous.

8 0
3 years ago
A student placed 18.5 g of glucose (C6H12O6) in a volumetric flask, added enough water to dissolve the glucose by swirling, then
mamaluj [8]

Answer:

1.30464 grams of glucose was present in 100.0 mL of final solution.

Explanation:

Molarity=\frac{moles}{\text{Volume of solution(L)}}

Moles of glucose = \frac{18.5 g}{180 g/mol}=0.1028 mol

Volume of the solution = 100 mL = 0.1 L (1 mL = 0.001 L)

Molarity of the solution = \frac{0.1028 mol}{0.1 L}=1.028 mol/L

A 30.0 mL sample of above glucose solution was diluted to 0.500 L:

Molarity of the solution before dilution = M_1=1.208 mol

Volume of the solution taken = V_1=30.0 mL

Molarity of the solution after dilution = M_2

Volume of the solution after dilution= V_2=0.500L = 500 mL

M_1V_1=M_2V_2

M_2=\frac{M_1V_1}{V_2}=\frac{1.208 mol/L\times 30.0 mL}{500 mL}

M_2=0.07248 mol/L

Mass glucose are in 100.0 mL of the 0.07248 mol/L glucose solution:

Volume of solution = 100.0 mL = 0.1 L

0.07248 mol/L=\frac{\text{moles of glucose}}{0.1 L}

Moles of glucose = 0.07248 mol/L\times 0.1 L=0.007248 mol

Mass of 0.007248 moles of glucose :

0.007248 mol × 180 g/mol = 1.30464 grams

1.30464 grams of glucose was present in 100.0 mL of final solution.

4 0
3 years ago
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