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Schach [20]
3 years ago
8

Select all that apply. The requirements for one type of atom to substitute for another in a solid solution are:

Chemistry
2 answers:
stiks02 [169]3 years ago
4 0

The correct answer is options c and e.  

A solid solution is basically a multi-component framework that comprises a mixture of two or more elements exhibiting a similar crystal lattice. The examples of solid solutions are alloys.  

The requirements for one kind of atom to substitute for another in a solid solution are:  

1. The size of the atom must be similar.  

2. The substituting atom must be from a similar group.  

Goryan [66]3 years ago
3 0

Answer:

An atom must be similar in size.

The substituting atom must be from the same group.

Explanation:

A solid solution is a solid mixture containing a minor component uniformly distributed within the crystal lattice of another component called the major component. Metal alloys are typical examples of a solid solution.

Note that only atoms of similar size can substitute each other in a solid solution. Usually atoms of elements in the same group have atomic sizes that vary within narrow ranges. Hence atoms of elements in the same group have similar atomic sizes and can substitute each other in a solid solution.

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3 years ago
A mixture of XO2 (P = 3.00 atm) and O2 (P = 1.00 atm) is placed in a container. This elementary reaction takes place at 27 °C: 2
sukhopar [10]

Answer:

a) \triangle G^{0} = 7.31 kJ/mol

b) K_{-1} = 0.0594 m^{-1} s^{-1}

Explanation:

Equation of reaction:

                                     2 XO_{2} (g) + O_{2} (g) \rightleftharpoons 2XO_{3} (g)

Initial pressure                  3              1              0

Pressure change             2P           1P             2P

Total pressure = (3-2P) + (1-P) + (2P)

Total Pressure = 3.75 atm

(3-2P) + (1-P) + (2P) = 3.75

4 - P = 3.75

P = 4 - 3.75

P = 0.25 atm

Let us calculate the pressure of each of the components of the reaction:

Pressure of XO2 = 3 - 2P = 3 - 2(0.25)

Pressure of XO2 =2.5 atm

Pressure of O2 = 1 - P = 1 -0.25

Pressure of O2 = 0.75 atm

Pressure of XO3 = 2P = 2 * 0.25

Pressure of XO3 = 0.5 atm

From the reaction, equilibrium constant can be calculated using the formula:

K_{p} = \frac{[PXO_{3}] ^{2} }{[PXO_{2}] ^{2}[PO_{2}] }

K_{p} = \frac{0.5^2}{2.5^2 *0.75} \\K_{p} = 0.0533 = K_{eq}

Standard free energy:

\triangle G^{0} = - RT ln k_{eq} \\\triangle G^{0} = -(0.008314*300* ln0.0533)\\\triangle G^{0} = 7.31 kJ/mol

b) value of k−1 at 27 °C, i.e. 300K

K_{1} = 7.8 * 10^{-2} m^{-2} s^{-1}

K_{c} = K_{p}RT\\K_{c} = 0.0533* 0.0821 * 300\\K_{c} = 1.313 m^{-1}

K_{-1} = \frac{K_{1} }{K_{c} } \\K_{-1} = \frac{7.8 * 10^{-2}  }{1.313 }\\K_{-1} = 0.0594 m^{-1} s^{-1}

6 0
3 years ago
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