Thank you for posting your question here. Below is the solution:
HNO3 --> H+ + NO3-
<span>HNO3 = strong acid so 100% dissociation </span>
<span>** one doesn't need to find the molarity of water since it is the solvent </span>
<span>0M HNO3 </span>
<span>1x10^-6M H3O+ </span>
<span>1x10^-6M NO3- </span>
<span>1x10^-8M OH-.....the Kw = 1x10^-14 = [H+][OH-] </span>
<span>you have 1x10^-6M H+ so, 1x10^-14 / 1x10^-6 = 1x10^-8M OH- </span>
<span>1x10^-6 Ba(OH)2 = strong base, 100% dissociation </span>
<span>1x10^-6M Ba2+ </span>
<span>2x10^-6M OH- since there are 2 OH- / 1 Ba2+ </span>
<span>0M Ba(OH)2 </span>
<span>5x10^-9M H3O+</span>
The question is missing the graphics required to answer which I have attached as an image.
There are four different representations of the orientation of water molecules around chloride anion. Let's first analyze the water molecule.
We have H-O-H as the structure of water. The oxygen atom is more electronegative than the hydrogen atoms, which results in a partial positive charge on the hydrogen atoms and a partial negative charge on the oxygen atom.
The chloride anion is a negative charge. Therefore, the water molecules should orient themselves with the hydrogen atoms facing the chlorine atom as the partial positive charge on the hydrogen atoms will be attracted to the negative charge of the chlorine atom.
The correct representation is shown in graph 3 which shows all hydrogen atoms facing the chlorine anion.
Answer:
(c) The retention time would be higher (d) The retention time would be lower.
Explanation:
For the polar solutes which were separated using the hydrophilic interaction chromatography (HILIC) with a strongly polar bonded phase, the retention time would be higher if eluent were changed from 80 vol% to 90 vol% acetonitrile in water.
However, for the polar solutes which were separated using the normal-phase chromatography on bare silica with methyl t=butyl ether and 2-propanol solvent, the retention time would be lower if the eluent were changed from 40 vol% to 60 vol% 2-propanol.
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