Answer:
this is the answer explanation of previous question. as what you say in comment i do that
120 grams of Carbon-14 decays to 15 grams in 17,190 years.
Answer:
A coffee cup calorimeter is great for measuring heat flow in a solution, but it can't be used for reactions that involve gases since they would escape from the cup. The coffee cup calorimeter can't be used for high-temperature reactions, either, because they would melt the cup.
To determine which order of the reaction it is, first we need to calculate the rate of change of moles.
the data is as follows
time 0 40 80 120 160
moles 0.100 0.067 0.045 0.030 0.020
Q1)
for the first 40 s change of moles ;
= -d[A] / t
= - (0.067-0.100)/40s
= 8.25 x 10⁻⁴ mol/s
for the next 40 s
= -(0.045-0.067)/40
= 5.5 x 10⁻⁴ mol/s
the 40 s after that
= -(0.030-0.045)/40 s
= 3.75 x 10⁻⁴ mol/s
k - rate constant
and A is the only reactant that affects the rate of the reaction
rate = k [A]ᵇ
8.25 × 10⁻⁴ mol/s = k [0.100 mol]ᵇ ----1
5.5 x 10⁻⁴ mol/s = k [0.067 mol]ᵇ -----2
divide the 2nd equation by the 1st equation
1.5 = [1.49]ᵇ
b is almost equal to 1
Therefore this is a first order reaction
Q2)
to find out the rate constant(k), we have to first state the equation for a first order reaction.
rate = k[A]ᵇ
As A is the only reactant thats considered for the rate equation.
Since this is a first order reaction,
b = 1
therefore the reaction is
rate = k[A]
substituting the values,
8.25 x 10⁻⁴ mol/s = k [0.100 mol]
k = 8.25 x 10⁻⁴ mol/s /0.100mol
= 8.25 x 10⁻³ s⁻¹
Cryo-EM is used to preserve and characterize cycled positive electrodes. Under regular cycling conditions, there isn't an intimate coating layer like CEI.A small electrical short can cause a stable conformal CEI to form in place. The conformal CEI's chemistry is revealed by EELS and cryo-(S)TEM.
It has been assumed that the intimate coating layer generated on the positive electrode, known as cathode electrolyte interphase (CEI), is crucial. However, there are still numerous questions about CEI. This results from the absence of useful instruments to evaluate the chemical and structural characteristics of these delicate interphases at the nanoscale. Here, using cryogenic electron microscopy, we establish a methodology to maintain the natural condition and directly see the interface on the positive electrode.
Learn more about Cathode electrolyte interphase here:
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