Answer:
- 10.555 kJ/mol.
Explanation:
∵ ∆G°rxn = ∆H°rxn - T∆S°rxn.
Where, ∆G°rxn is the standard free energy change of the reaction (J/mol).
∆H°rxn is the standard enthalpy change of the reaction (J/mol).
T is the temperature of the reaction (K).
∆S°rxn is the standard entorpy change of the reaction (J/mol.K).
∵ ∆H°rxn = ∑∆H°products - ∑∆H°reactants
<em>∴ ∆H°rxn = (2 x ∆H°f NOCl) - (1 x ∆H°f Cl₂) - (2 x ∆H°f NO) </em>= (2 x 51.71 kJ/mol) - (1 x 0) - (2 x 90.29 kJ/mol) = - 77.16 kJ/mol.
∵ ∆S°rxn = ∑∆S°products - ∑∆S°reactants
<em>∴ ∆S°rxn = (2 x ∆S° NOCl) - (1 x ∆S° Cl₂) - (2 x ∆S° NO) </em>= (2 x 261.6 J/mol.K) - (1 x 223.0 J/mol.K) - (2 x 210.65 J/mol.K) =<em> - 121.1 J/mol.K. = - 0.1211 kJ/mol.K.</em>
<em></em>
∵ ∆G°rxn = ∆H°rxn - T∆S°rxn.
<em>∴ ∆G°rxn = ∆H°rxn - T∆S°rxn </em>= (- 77.16 kJ/mol) - (550 K)(- 0.1211 kJ/mol.K) = <em>- 10.555 kJ/mol.</em>
Answer:
A. 6N
B. 4H, 2O
C. 4H, 4N, 12O
D. 2Ca, 4O, 4H
E. 3Ba, 6Cl, 18O
F. 5Fe, 10N, 30O
G. 12Mg, 8P, 32O
H. 4N, 16H, 2S, 8O
I. 12Al, 18Se, 72O
J. 12C, 32H
I am 90% sure this is correct
We have Kc = 4.2 x 10^-2 (given but missing in the question)
and When the balanced equation for this reaction is:
PCl5(g) ↔ PCl3(g) + Cl2(g)
so, according to the Kc formula:
Kc = the concentration of products / the concentration of the reactants
so, to get the concentration of the reactants in equilibrium, the concentration of the products / the concentration of the reactants should equal the Kc value which is given in the question (missing in your question).
So by substitution in Kc formula:
Kc = [PCl3]*[Cl2] / [PCl5]
4.2 x 10^-2 = 0.18 * 0.25 /[PCl5]
∴[PCl5] = 0.18*0.25 / 4.2x10^-2 = 1.07
So the concentration of the reactants in equilibrim = 1.07
The molecules vibrate faster and space between atoms increase
