<span>Answer is: Van't Hoff factor
(i) for this solution is 1.051 .
Change in boiling point from pure solvent to solution: ΔT
=i · Kb · b.
Kb - </span><span>molal boiling point elevation constant</span><span> is 0.512°C/m.
b - molality, moles of solute per kilogram of solvent.
b = 1.26 m.
ΔT = 101.63°C - 100</span>°C = 1.63°C.
i = 1.63°C ÷ (0.512°C/m · 1.26 m).
i = 1.051.
Answer:
N₂ = 0.7515atm
O₂ = 0.1715atm
NO = 0.0770atm
Explanation:
For the reaction:
N₂(g) + O₂(g) ⇄ 2NO(g)
Where Kp is defined as:
Pressures in equilibrium are:
N₂ = 0.790atm - X
O₂ = 0.210atm - X
NO = 2X
Replacing in Kp:
0.0460 = [2X]² / [0.790atm - X] [0.210atm - X]
0.0460 = 4X² / 0.1659 - X + X²
0.0460X² - 0.0460X + 7.6314x10⁻³ = 4X²
-3.954X² - 0.0460X + 7.6314x10⁻³ = 0
Solving for X:
X = - 0.050 → False answer. There is no negative concentrations.
X = <em>0.0385 atm</em> → Right answer.
Replacing for pressures in equilibrium:
N₂ = 0.790atm - X = <em>0.7515atm</em>
O₂ = 0.210atm - X = <em>0.1715atm</em>
NO = 2X = <em>0.0770atm</em>
Answer:
The activation energy is 164.02 kJ/mol
Explanation:
Log (k2/k1) = Ea/2.303R × [1/T1 - 1/T2]
k1 = 8.9×10^-4 s^-1
k2 = 9.83×10^-3 s^-1
R = 8.314 J/mol.K
T1 = 540 K
T2 = 578 K
Log (9.83×10^-3/8.9×10^-4) = Ea/2.303×8.314 × [1/540 - 1/578]
1.043 = 6.359×10^-6Ea
Ea = 1.043/6.359×10^-6 = 164020 J/mol = 164020/1000 = 164.02 kJ/mol
Scientific Law is proven by the demoonstration of an irrefutable fact - for instance The Law of Gravity.
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