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3 years ago

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The solubility of kcl in ethanol is 0.25 g / 100 ml at 25 oc. how does this compare to the solubility of kcl in water?

1 answer:

Furkat [3]3 years ago

8 0

Solubility data of a certain solute with a certain solvent is empirical. There are constant values for this at varying temperatures. For KCl in water at 25°C, the solubility is 35.7 g/100 mL of water. When you compare this with the solubility data of KCl with ethanol, this means that KCl is more soluble in water than in ethanol. This is true because KCl is an ionic salt which is very soluble in water.

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Calculate the standard reaction Gibbs free energy for the following cell reactions: (a) 2 Ce41(aq) 1 3 I2(aq) S 2 Ce31(aq) 1 I32

Law Incorporation [45]

<u>Answer:</u>

<u>For a:</u> The standard Gibbs free energy of the reaction is -347.4 kJ

<u>For b:</u> The standard Gibbs free energy of the reaction is 746.91 kJ

<u>Explanation:</u>

Relationship between standard Gibbs free energy and standard electrode potential follows:

$\Delta G^o=-nFE^o_{cell}$ ............(1)

<u>For a:</u>

The given chemical equation follows:

$2Ce^{4+}(aq.)+3I^{-}(aq.)\rightarrow 2Ce^{3+}(aq.)+I_3^-(aq.)$

<u>Oxidation half reaction:</u> $Ce^{4+}(aq.)\rightarrow Ce^{3+}(aq.)+e^-$ ( × 2)

<u>Reduction half reaction:</u> $3I^_(aq.)+2e^-\rightarrow I_3^-(aq.)$

We are given:

$n=2\\E^o_{cell}=+1.08V\\F=96500$

Putting values in equation 1, we get:

$\Delta G^o=-2\times 96500\times (+1.80)=-347,400J=-347.4kJ$

Hence, the standard Gibbs free energy of the reaction is -347.4 kJ

<u>For b:</u>

The given chemical equation follows:

$6Fe^{3+}(aq.)+2Cr^{3+}+7H_2O(l)(aq.)\rightarrow 6Fe^{2+}(aq.)+Cr_2O_7^{2-}(aq.)+14H^+(aq.)$

<u>Oxidation half reaction:</u> $Fe^{3+}(aq.)\rightarrow Fe^{2+}(aq.)+e^-$ ( × 6)

<u>Reduction half reaction:</u> $2Cr^{2+}(aq.)+7H_2O(l)+6e^-\rightarrow Cr_2O_7^{2-}(aq.)+14H^+(aq.)$

We are given:

$n=6\\E^o_{cell}=-1.29V\\F=96500$

Putting values in equation 1, we get:

$\Delta G^o=-6\times 96500\times (-1.29)=746,910J=746.91kJ$

Hence, the standard Gibbs free energy of the reaction is 746.91 kJ

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Answer:

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Explanation:

Step 1: Given data

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