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Olin [163]
4 years ago
8

Draw the structures of the major and minor organic products formed when hbr reacts with 2,4,4-trimethyl-2-pentene in the presenc

e of peroxides. when drawing hydrogen atoms on a carbon atom, either include all hydrogen atoms or none on that carbon atom, or your structure may be marked incorrect.

Chemistry
1 answer:
OLEGan [10]4 years ago
3 0
Answer : The major and minor products of 2,4,4-trimethy-2-pentene will be a tertiary radical of Br which will be in major quantity whereas secondary radical of Br will be in minor quantity.

As the reaction follows anti-markonikov's rule the radical formed in tertiary state will be more stable and the secondary state will be much unstable as compared to tertiary state.

Note -  The structures are arranged in the attachment

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1. Gather all the information in one place with molar masses above the formulas and masses below them.  

MM:        17.03    32.00     30.01

              4NH₃  +  5O₂ ⟶ 4NO + 6H₂O

Mass/g:    1.5        1.85

2. Calculate the moles of each reactant  

\text{moles of NH}_{3} = \text{1.5 g NH}_{3} \times \dfrac{\text{1 mol NH}_{3}}{\text{17.03 g NH}_{3}} = \text{0.0881 mol NH}_{3}\\\\\text{moles of O}_{2} = \text{1.85 g O}_{2} \times \dfrac{\text{1 mol O}_{2}}{\text{32.00 g O}_{2}} = \text{0.057 81 mol O}_{2}

3. Calculate the moles of NO we can obtain from each reactant

From NH₃:

The molar ratio is 4 mol NO:4 mol NH₃

\text{Moles of NO} = \text{0.0881 mol NH}_{3} \times \dfrac{\text{4 mol NO}}{\text{4 mol NH}_{3}} = \text{0.0881 mol NO}

From O₂:

The molar ratio is 4 mol NO:5 mol O₂

\text{Moles of NO} =  \text{0.057 81 mol O}_{2}\times \dfrac{\text{4 mol NO}}{\text{5 mol O}_{2}} = \text{0.046 25 mol NO}

4. Identify the limiting and excess reactants

The limiting reactant is O₂ because it gives the smaller amount of NO.

The excess reactant is NH₃.

5. Calculate the mass of NO formed

\text{Mass of NO} = \text{0.046 25 mol NO}\times \dfrac{\text{30.01 g NO}}{\text{1 mol NO}} = \textbf{1.39 g NO}

6. Calculate the moles of NH₃ reacted

The molar ratio is 4 mol NH₃:5 mol O₂

\text{Moles reacted} = \text{0.057 81 mol O}_{2} \times \dfrac{\text{4 mol NH}_{3}}{\text{5 mol O}_{2}} = \text{0.046 25 mol NH}_{3}

7. Calculate the mass of NH₃ reacted

\text{Mass reacted} = \text{0.046 25 mol NH}_{3} \times \dfrac{\text{17.03 g NH}_{3}}{\text{1 mol NH}_{3}} = \text{0.7876 g NH}_{3}

8. Calculate the mass of NH₃ remaining

Mass remaining = original mass – mass reacted = (1.5 - 0.7876) g = 0.7 g NH₃

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